CAS 776-74-9 MFCD00000134-Bromodiphenylmethane 二苯基溴甲烷 -LabNovo

Bromodiphenylmethane 二苯基溴甲烷

CAS 776-74-9 MFCD00000134

化学结构图

SMILES: BrC(c1ccccc1)c1ccccc1

化学属性

Mol. Formula	C13H11Br
Mol. Weight	247.13
Boiling Point	184
Melting Point	35-39
Flash Point	>110°(230°F)
TSCA	Yes
Solubility	不溶
Density	0,9 g/cm3
Stability	对湿度敏感

别名和识别编码

Chemical Name	Bromodiphenylmethane
Synonym	1,1’-(bromomethylene)bis-benzen 9,10-Dihydro-4H-Benzo[4,5] Cyclohepta[1,2-B] Thiophene ALPHA-BROMODIPHENYLMETHANE BENZHYDRYL BROMIDE BROMODIPHENYLMETHANE BROMODIPHENYLMETHANE CRYSTALLINE Benzene, 1,1-(bromomethylene)bis- Benzhydryl bromide, (Bromodiphenylmathane Benzhydryl bromide, Diphenylbromomethane Benzhydryl Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	776-74-9
PubChem Substance ID	236603
EC Number	212-279-8
Beilstein Registry Number	5,592
MDL Number	MFCD00000134
Reaxys-RN	638544
Chemical Name Translation	二苯基溴甲烷
InChIKey	DLCYFIIONMLNAJ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00224108
InChI	InChI=1S/C13H11Br/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H

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安全信息

GHS Symbol

WGK Germany3

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Hazard Codes

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P302+P361+P354
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P354+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P316
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P403+P233
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word

RTECSPA5350000

Storage condition +4°C 0-10 0-10°C 4 4℃ Moisture Sensitive 储存温度2-8°C 储存温度2-8°C,充氩保存

UN Number UN 1770 8/PG 2 1770

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

Packing GroupII

Hazard Class8

Warnings 危化品目录(2015)

Restrict 危险品

其他信息

灭火剂:干粉、二氧化碳
可燃性危险特性:可燃; 遇水分解有毒溴化氢气体
Alfa Aesar:溴化二苯甲基,95% Benzhydryl bromide, 95%(776-74-9)
Sigma Aldrich:776-74-9(sigmaaldrich)
类别:腐蚀物品
方法一:二苯甲烷在光照下加热，滴加溴素，在130℃保温1h，即得溴代二苯甲烷。
图谱信息:二苯基溴甲烷(776-74-9)质谱(MS) 二苯基溴甲烷(776-74-9)核磁图( 13 CNMR) 二苯基溴甲烷(776-74-9)红外图谱(IR2) 二苯基溴甲烷(776-74-9)红外图谱(IR1)
用途一:医药中间体。与无水哌嗪、苯丙烯氯缩合可得长效多功能的血管收缩拮抗剂桂益嗪。
上游原料:溴 --> 二苯基甲烷
MSDS 信息:二苯甲基溴(776-74-9).msds
外观性质:带刺激性气味的固体，有催泪性。
储运特性:库房通风低温干燥; 与氧化剂分开存放
海关编码:29036990
F:19-21
下游产品:桂利嗪 --> 艾捉非尼 --> 依巴斯汀
MOL 文件:776-74-9.mol
二苯基溴甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0586 α-溴二苯基甲烷 alpha-Bromodiphenylmethane 500G 1800元 2014/06/02 B0586 α-溴二苯基甲烷 alpha-Bromodiphenylmethane 25G 228元 2010/06/21 373465000 二苯基溴甲烷 Bromodiphenylmethane 90% 500 GR 1432元
Acros Organics:溴代二苯甲烷 Bromodiphenylmethane, 90%(776-74-9)
TCI Shanghai:α-溴二苯基甲烷 alpha-Bromodiphenylmethane,>;97.0%(T)(776-74-9)