Desyl Bromide 2-溴-2-苯基乙酰苯

CAS 1484-50-0 MFCD00000136

化学结构图

1484-50-0
SMILES: O=C(c1ccccc1)C(Br)c1ccccc1

化学属性

Mol. FormulaC14H11BrO
Mol. Weight275.15
Melting Point56-58 °C(lit.)
TSCAYes

别名和识别编码

Chemical NameDesyl Bromide
Synonym A-BROMODESOXY BENZOIN 2-溴-2-苯基苯乙酮 DESYL BROMIDE 溴去氧安息香 1,2-Diphenyl-2-bromoethanone ALPHA-BROMO-ALPHA-PHENYLACETOPHENONE 2-BROMO-2-PHENYLACETOPHENONE Phenyl(α-bromobenzyl) ketone 2-Bromo-2-phenylacetophenone2-Bromo-1,2-diphenylethan-1-one 2-bromo-1,2-diphenylethan-1-one 2-溴-2-苯基乙酰苯 α-Bromodeoxybenzoin AKOS BBS-00000845 2-BROMO-2-PHENYLACETOPHENONE 97% 2-Bromo-1,2-diphenylethanone 2-Bromo-2-phenylacetophenone 2-bromo-1,2-diphenyl-ethanon
MDL NumberMFCD00000136
PubChem Substance ID102630
CAS Number1484-50-0
EC Number216-057-1
Chemical Name Translation2-溴-2-苯基乙酰苯
InChIKeyZFFBIQMNKOJDJE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00223965
Reaxys-RN780486
InChIInChI=1S/C14H11BrO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13H
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分类

  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

相关文献及参考

  • Beil. 7 ,436
  • Corp MSDS 1 (1), 1036:C / RegBook 1 (2), 1625:D / Structure Index 1 , 254:A:2

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
UN Number 3261 1759 UN3261
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Packing GroupII
Storage condition 储存温度2-8℃ 0-6°C
Hazard Class8

其他信息

  • Acros Organics:2-Bromo-2-phenylacetophenone, 97%(1484-50-0)
  • MOL 文件:1484-50-0.mol
  • Sigma Aldrich:1484-50-0(sigmaaldrich)
  • 2-溴-2-苯基乙酰苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 403170050 2-溴-2-苯基乙酰苯 2-Bromo-2-phenylacetophenone 97% 5 GR 780元 2010/06/21 403170250 2-溴-2-苯基乙酰苯 2-Bromo-2-phenylacetophenone 97% 25 GR 2774元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12

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