安全信息
WGK Germany | 3 |
Hazard Codes |
F+,Xn,N
F,Xn,N
T,N,Xn,F,F+
T;N |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H301+H331
- H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
- H319 Causes serious eye irritation 严重刺激眼睛
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere 通过破坏上层大气臭氧层而危害公众健康和环境。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H335+H336
- H302+H332
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Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
RTECS | PA4900000 |
Precautionary statements | |
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P305+P351+P338
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
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Signal word |
Danger |
Safety Statements | |
- S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
- S7 Keep container tightly closed 保存在严格密闭容器中;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S15 Keep away from heat 远离热源;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
- S24 Avoid contact with skin 避免皮肤接触;
- S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护;
- S59 Refer to manufacturer/supplier for information on recovery/recycling 参考生产厂家/供货商提供的回收/再生利用信息;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
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Risk Statements | |
- R12 Extremely flammable 极端易燃
- R48/20
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R59 Dangerous for the ozone layer 对臭氧层有危害
- R38 Irritating to skin 刺激皮肤
- R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R50 Very toxic to aquatic organisms 对水生生物极毒
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
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UN Number |
1062/1581/1647/1955
UN 1062 2.3 |
Storage condition |
冰箱2-8℃保存
2-8°C |
Hazard Class | 2.3 |
Warnings |
危化品目录(2015) |
TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 3250 mg/kg/13W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria
Gastrointestinal - peritonitis
Gastrointestinal - tumors
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E.
First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year:
72,262,1984
TYPE OF TEST : LCLo - L
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 300 ppm/9H
TOXIC EFFECTS :
Behavioral - muscle weakness
Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis)
Skin and Appendages - hair
REFERENCE :
XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC)
Volume(issue)/page/year: 185,1,1929
TYPE OF TEST : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Human
DOSE/DURATION : 35 ppm
TOXIC EFFECTS :
Behavioral - anorexia (human)
Gastrointestinal - nausea or vomiting
Skin and Appendages - corrosive (after topical exposure)
REFERENCE :
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Human - child
DOSE/DURATION : 1 gm/m3/2H
TOXIC EFFECTS :
Blood - change in clotting factors
REFERENCE :
NHOZAX Nippon Hoigaku Zasshi. Japanese Journal of Legal Medicine. (Nippon
Hoi Gakkai, c/o Tokyo Daigaku Igakubu Hoigaku Kyoshitsu, 7-3-1, Hongo,
Bunkyo-ku, Tokyo 113, Japan) V.1- 1944- Volum
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 135 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
INHEAO Industrial Health. (National Institute of Industrial Health, 6-21-1
Nagao, Tama-ku, Kawasaki, 213 Japan) V.1- 1963- Volume(issue)/page/year:
26,101,1988
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : R
TYPE OF TEST : Mutation in microorganisms
TEST SYSTEM : Bacteria - Salmonella typhimurium
DOSE/DURATION : 5 gm/m3
REFERENCE :
MUREAV Mutation Research.
TYPE OF TEST : Sister chromatid exchange
TEST SYSTEM : Human Lymphocyte
DOSE/DURATION : 5 mg/L
REFERENCE :
TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. (Alan R. Liss, Inc.,
41 E. 11th St., New York, NY 10003) V.1- 1980- Volume(issue)/page/year:
10,21,1990
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TYPE OF TEST : Mutation in microorganisms
TEST SYSTEM : Bacteria - Salmonella typhimurium
DOSE/DURATION : 400 ppm
REFERENCE :
DHEFDK HEW Publication (FDA. United States). (Washington, DC) ?-1979(?).
For publisher information, see HPFSDS. Volume(issue)/page/year:
FDA-78-1046,1978
TYPE OF TEST : Specific locus test
ROUTE OF EXPOSURE : Inhalation
TEST SYSTEM : Insect - Drosophila melanogaster
DOSE/DURATION : 8 mg/L/1H (Continuous)
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE
Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 192,131,1987
TYPE OF TEST : Mutation test systems - not otherwise specified
TEST SYSTEM : Bacteria - Salmonella typhimurium
DOSE/DURATION : 3 pph
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For
publisher information, see EMMUEG. Volume(issue)/page/year: 9,171,1987
TYPE OF TEST : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE : Inhalation
TEST SYSTEM : Insect - Drosophila melanogaster
DOSE/DURATION : 150 mg/m3/6H
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE
Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 113,272,1983
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