3-Methylbenzyl Bromide 3-甲基苄溴

CAS 620-13-3 MFCD00000177

化学结构图

620-13-3
SMILES: Cc1cccc(CBr)c1

化学属性

Mol. FormulaC8H9Br
Mol. Weight185.06
Refractive index1.5640 to 1.5680
Boiling Point185
Density1.370
Flash Point82°C(lit.)
TSCAYes
Solubility难溶

别名和识别编码

Chemical Name3-Methylbenzyl Bromide
Synonym 1-(BROMOMETHYL)-3-METHYLBENZENE 1-bromomethyl-3-methyl-benzene 3-(Bromomethyl)toluene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} m-Xylene, alpha-bromo- {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} alpha-bromo-m-xylen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} alpha-Dibromo-m-xylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemblink} alpha-Bromo-m-xylene; m-Xylyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {ALFA} alpha-Bromo-m-xylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} M-METHYLBENZYL BROMIDE {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number620-13-3
PubChem Substance ID87563962
EC Number210-625-2
MDL NumberMFCD00000177
Beilstein Registry Number2076425
Reaxys-RN2076425
Merck Number10090
Alfabeta NameBROMOMETHYLMETHYLBENZENE 13()---
Chemical Name Translation3-甲基苄溴
LabNetwork Molecule IDLN00174260
InChIInChI=1S/C8H9Br/c1-7-3-2-4-8(5-7)6-9/h2-5H,6H2,1H3
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Aldrich MSDS 1 , 296:A / Corp MSDS 1 (1), 591:A / FT-IR 1 (1), 985:D / FT-IR 2 (2), 1698:A / FT-NMR 1 (2), 83:B / IR-Spectra (3), 594:F / IR-Spectra (2), 530:A / NMR-Reference 2 (1), 788:C / RegBook 1 (1), 1175:G / Sigma FT-IR 1 (2), 348:C / Structure Index 1 , 180:C:6 / Vapor Phase 3 , 903:B
  • Beil. 5 ,374
  • Merck 14 ,10090
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 C
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S4 Keep away from living quarters 远离生活区；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
RTECSCY9039200
UN Number 1701
Packing GroupII
Warnings IRRITANT
Hazard Class6.1
Storage condition +4°C 4℃

其他信息

  • 3-甲基苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1010 α-溴间二甲苯 alpha-Bromo-m-xylene 500G 6560元 2014/06/02 B1010 α-溴间二甲苯 alpha-Bromo-m-xylene 25G 728元 2014/06/02 B3585 α-溴-间二甲苯 alpha-Bromo-m-xylene 25G 1950元
  • MOL 文件:620-13-3.mol
  • 下游产品:
  • Hazard Note:Corrosive
  • 图谱信息:3-甲基苄溴(620-13-3)质谱(MS) 3-甲基苄溴(620-13-3)核磁图( 1 HNMR) 3-甲基苄溴(620-13-3)红外图谱(IR1) 3-甲基苄溴(620-13-3)核磁图( 13 CNMR)
  • Sigma Aldrich:620-13-3(sigmaaldrich)
  • Acros Organics:alpha-溴间甲二苯 alpha-Bromo-m-xylene, 96%(620-13-3)
  • 检测方法:GC,NMR
  • Alfa Aesar:3-甲基苄溴,97% 3-Methylbenzyl bromide, 97%(620-13-3)
  • MSDS 信息:m-Xylyl bromide(620-13-3).msds
  • TCI Shanghai:α-溴间二甲苯 alpha-Bromo-m-xylene,>;80.0%(GC)(620-13-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C8 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C7