1,3-Bis(bromomethyl)benzene 1,3-二(溴甲基)苯

CAS 626-15-3 MFCD00000178

化学结构图

626-15-3
SMILES: BrCc1cccc(CBr)c1

化学属性

Mol. FormulaC8H8Br2
Mol. Weight263.96
Boiling Point258.2°C at 760 mmHg
Melting Point74-77°C
TSCAYes
Solubilitydioxane: 0.1 g/mL, clear, colorless

别名和识别编码

Chemical Name1,3-Bis(bromomethyl)benzene
Synonym 1,3-Bis(bromomethyl)benzene {LY} 1,3-Bis(bromomethyl)benzene {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(bromomethyl)b
CAS Number626-15-3
PubChem Substance ID87566928
EC Number210-931-6
Beilstein Registry Number971085
MDL NumberMFCD00000178
Reaxys-RN971085
Chemical Name Translation1,3-二(溴甲基)苯
InChIKeyOXHOPZLBSSTTBU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115464
InChIInChI=1S/C8H8Br2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6H2
Canonical SMILESBrCC1=CC(CBr)=CC=C1
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: III/31b
  • Short: IV/8A
  • Reductive coupling has been used in a relatively high-yielding route to [2,2]-m-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc. Perkin 1, 2029 (1991).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes 6.1 Xi
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P342+P311
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {TCI}
UN Number 2928 3448 UN 3448 6.1/PG 2 UN3261
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Packing GroupII
Hazard Class6.1/8
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • MSDS 信息:1,3-Bis(bromomethyl)benzene(626-15-3).msds
  • F:8-19-21
  • TCI Shanghai:α、α-二溴间二甲苯 alpha,alpha'-Dibromo-m-xylene,>;97.0%(GC)(626-15-3)
  • 1,3-二(溴甲基)苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0215 α,α-二溴间二甲苯 alpha,alpha'-Dibromo-m-xylene 5G 335元 2014/06/02 D0215 α,α-二溴间二甲苯 alpha,alpha'-Dibromo-m-xylene 25G 991元 2010/05/25 B24959 间二溴苄 (1,3-二(溴甲基)苯  , 97%   m-Xylylene dibromide, 97% 250g 8652元
  • 海关编码:29036990
  • Alfa Aesar:间二溴苄(1,3-二(溴甲基)苯,97% m-Xylylene dibromide, 97%(626-15-3)
  • Sigma Aldrich:626-15-3(sigmaaldrich)
  • MOL 文件:626-15-3.mol
  • 图谱信息:1,3-二(溴甲基)苯(626-15-3)核磁图( 13 CNMR) 1,3-二(溴甲基)苯(626-15-3)红外图谱(IR1) 1,3-二(溴甲基)苯(626-15-3)Raman光谱 1,3-二(溴甲基)苯(626-15-3)质谱(MS) 1,3-二(溴甲基)苯(626-15-3)红外图谱(IR2) 1,3-二(溴甲基)苯(626-15-3)核磁图( 1 HNMR)

系列性分类


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