1-Bromododecane 溴代十二烷

CAS 143-15-7 MFCD00000225

化学结构图

143-15-7
SMILES: CCCCCCCCCCCCBr

化学属性

Mol. FormulaC12H25Br
Mol. Weight249.24
Density1.038
Vapor Density8.6 (vs air)
Refractive index1.4580 to 1.4600
Boiling Point134-135°C at 6 mmHg
Melting Point−11-−9 °C
Flash Point113°C
TSCAYes
Solubility不溶
Stability对光敏感
Appearance 无色至淡黄色液体。熔点-9.5℃,沸点276℃,200-201℃(13.3kPa),139℃(1.33kPa),134-135℃(0.8kPa),相对密度1.0399(20/4℃),折光率1.4583,闪点110℃。能与丙酮混溶,溶于乙醇,乙醚,不溶于水。有椰子样气味。有刺激性。
pH:A

别名和识别编码

Chemical Name1-Bromododecane
Synonym 1-Bromododecane {LY} 1-Bromododecane {} {LY} 1-Bromododecane {} {} {LY} 1-Bromododecane {} {} {} {LY} 1-Bromododecane {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromododecane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Brom
MDL NumberMFCD00000225
CAS Number143-15-7
EC Number205-587-9
Beilstein Registry Number506159
Merck Number5389
PubChem Substance ID8919
Reaxys-RN506159
Chemical Name Translation溴代十二烷
LabNetwork Molecule IDLN00195576
InChIInChI=1S/C12H25Br/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
Canonical SMILESCCCCCCCCCCCCBr
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用作溶剂,还可用于合成阻燃剂三(十二烷基硫醇)锑; 抗氧剂十二烷基硫醇; 表面活性剂十二烷基二甲基苄基氯化氨(洁尔灭); 苯扎溴铵,以及其他阻燃剂和表面活性剂等。

相关文献及参考

  • Short: IV/18A
  • Merck: 14,5389
  • Merck: 14,5389 Beilstein:1(2)133
  • Short:
  • Short: III/38B
  • Short: IV/16
  • Short: IV/18B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 溴代十二烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30026624 1-溴化十二烷 25ml 35元 2011/04/16 B0587 1-溴十二烷 1-Bromododecane 500ML 490元 2011/04/16 B0587 1-溴十二烷 1-Bromododecane 25ML 120元
  • 用途一:主要用于有机合成,在医药上用于合成消毒药新洁尔灭、度米芬等
  • Alfa Aesar:1-溴十二烷,98% 1-Bromododecane, 98%(143-15-7)
  • 方法一:1.氢溴酸法 由月桂醇(正十二醇)与氢溴酸作用而得。将月桂醇加入搪瓷玻璃反应锅,搅拌冷却,慢慢加入硫酸。搅拌1h,再加入氢溴酸。温度逐渐提高到90-95℃,搅拌反应8h。反应完毕,降温至30℃静置8h 。分出酸层,油层用稀碱液调节pH至8,分去碱液,以50%乙醇洗涤。减压蒸馏,收集140-200℃(3.33kPa)馏分得精制的1-溴十二烷。2.溴化钠法3.溴化法
  • 用途三:用作溶剂,还可用于合成阻燃剂三(十二烷基硫醇)锑、抗氧剂十二烷基硫醇、表面活性剂十二烷基二甲基苄基氯化氨(洁尔灭)、苯扎溴铵,以及其他阻燃剂和表面活性剂等。
  • 能与丙酮混溶,溶于乙醇,乙醚,不溶于水。有椰子样气味。有刺激性。
  • 检测方法:GC,NMR
  • 用途二:用作溶剂,也用于有机合成
  • MOL 文件:143-15-7.mol
  • 图谱信息:溴代十二烷(143-15-7)红外图谱(IR2) 溴代十二烷(143-15-7)红外图谱(IR1) 溴代十二烷(143-15-7)核磁图( 13 CNMR) 溴代十二烷(143-15-7)质谱(MS) 溴代十二烷(143-15-7)Raman光谱 溴代十二烷(143-15-7)核磁图( 1 HNMR)
  • 下游产品:十二烷基二甲基苄基溴化铵 --> 3-十二烷基噻吩 --> 三月桂胺 --> 十二烷基磺酸钠 --> 十二硫醇
  • Sigma Aldrich:143-15-7(sigmaaldrich)
  • TCI Shanghai:1-溴十二烷 1-Bromododecane,>;98.0%(GC)(143-15-7)
  • 常规方法:200kg塑料桶装。
  • 上游原料:氢溴酸 --> 十二醇
  • 蒸气密度:8.6 (vs air)
  • 用途四:用作溶剂,还可用于合成阻燃剂三(十二烷基硫醇)锑; 抗氧剂十二烷基硫醇; 表面活性剂十二烷基二甲基苄基氯化氨(洁尔灭); 苯扎溴铵,以及其他阻燃剂和表面活性剂等。
  • Acros Organics:1-溴十二烷 1-Bromododecane, 98%(143-15-7)
  • F:19
  • 海关编码:29033036
  • 防护措施:有麻醉作用。
  • MSDS 信息:1-Bromododecane(143-15-7).msds

系列性分类