2-Phenoxyethylbromide 2-苯氧乙基溴

CAS 589-10-6 MFCD00000234

化学结构图

589-10-6
SMILES: BrCCOc1ccccc1

化学属性

Mol. FormulaC8H9BrO
Mol. Weight201.06
Density1.35
Boiling Point144°C at 760 mmHg
Melting Point31-34°C
Flash Point65°C
TSCAYes
Refractive index1.555-1.557
Stability对光敏感

别名和识别编码

Chemical Name2-Phenoxyethylbromide
CAS Number589-10-6
Synonym (2-Bromoethoxy)benzene {LY} (2-Bromoethoxy)benzene {} {LY} (2-Bromoethoxy)benzene {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoethoxy)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Bromoet
EC Number209-634-4
Beilstein Registry Number6,142
MDL NumberMFCD00000234
PubChem Substance ID68526
Chemical Name Translation2-苯氧乙基溴
Reaxys-RN508290
InChIKeyJJFOBACUIRKUPN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224482
InChIInChI=1S/C8H9BrO/c9-6-7-10-8-4-2-1-3-5-8/h1-5H,6-7H2
Canonical SMILESBrCCOC1=CC=CC=C1
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分类

  • {SNA} Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • Aromatics
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment

产品应用

  • 医药中间体。

相关文献及参考

  • Short: EINECS
  • Short: IV/6
  • Short: III/20b
  • Beilstein:6,142

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi Xn
UN Number 1325
Packing GroupII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class4.1

其他信息

  • Alfa Aesar:2-苯氧基乙基溴,98% 2-Phenoxyethyl bromide, 98%(589-10-6)
  • 2-苯氧乙基溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0931 β-溴苯乙醚 beta-Bromophenetole 25G 558元 2010/06/21 107250050 2-苯氧乙基溴 beta-Bromophenetole 98% 5 GR 188元 2010/06/21 107251000 2-苯氧乙基溴 beta-Bromophenetole 98% 100 GR 1837元
  • 用途一:用于萘法唑酮、苯氧哌咪酮等原料药合成
  • Sigma Aldrich:589-10-6(sigmaaldrich)
  • 海关编码:29093038
  • 下游产品:2-苯氧基乙胺
  • 图谱信息:2-苯氧乙基溴(589-10-6)质谱(MS) 2-苯氧乙基溴(589-10-6)核磁图( 1 HNMR) 2-苯氧乙基溴(589-10-6)核磁图( 13 CNMR) 2-苯氧乙基溴(589-10-6)Raman光谱 2-苯氧乙基溴(589-10-6)红外图谱(IR1) 2-苯氧乙基溴(589-10-6)红外图谱(IR2)
  • Hazard Note:Irritant
  • 上游原料:苯乙醚 --> 二溴乙烷
  • 方法一:由苯酚和二溴乙烷反应而得。将苯酚、二溴乙烷、氢氧化钠放在反应锅内搅拌混合，于110℃反应6h，回收二溴乙烷，回收量约为60%，用5%氢氧化钠溶液和水洗涤，分取油层，减压蒸馏，收集130-150℃（6.7kPa）馏分即得（2-溴乙氧基）苯。 用途：医药中间体。 #EndEditable "Content"
  • Acros Organics:beta-溴苯乙醚 beta-Bromophenetole, 98%(589-10-6)
  • 用途二:医药中间体。 #EndEditable "Content"
  • TCI Shanghai:2-溴乙基苯基醚 beta-Bromophenetole,>;97.0%(GC)(589-10-6)
  • MOL 文件:589-10-6.mol
  • MSDS 信息:beta-Bromophenetole(589-10-6).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C9 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides

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