Diethyl (2-bromoethyl)phosphonate 2-溴乙基膦酸二乙酯

CAS 5324-30-1 MFCD00000239

化学结构图

5324-30-1
SMILES: CCOP(=O)(CCBr)OCC

化学属性

Mol. FormulaC6H14BrO3P
Mol. Weight245.05
Refractive index1.4590 to 1.4620
Density1.3740
Boiling Point253.9 °C at 760 mmHg
Flash Point>110°(230°F)
TSCANo

别名和识别编码

Chemical Namediethyl (2-bromoethyl)phosphonate
MDL NumberMFCD00000239
CAS Number5324-30-1
Synonym Diethyl (2-bromoethyl)phosphonate {LY} Diethyl (2-bromoethyl)phosphonate {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diethyl (2-bromoethyl)
PubChem Substance ID79218
Beilstein Registry Number1766077
EC Number226-193-3
Reaxys-RN1766077
Chemical Name Translation2-溴乙基膦酸二乙酯
InChIKeyPINITSMLVXAASM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00241002
InChIInChI=1S/C6H14BrO3P/c1-3-9-11(8,6-5-7)10-4-2/h3-6H2,1-2H3
Canonical SMILESBrCCP(OCC)(OCC)=O
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents

相关文献及参考

  • Beilstein:4(4)3536

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Storage condition 2-8°C {LY} 2-8°C Refrigerator {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
Hazard Codes Xi

其他信息

  • 2-溴乙基膦酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B1781 2-溴乙基磷酸二乙酯 Diethyl 2-Bromoethylphosphonate 5G 437元 2011/04/16 B1781 2-溴乙基磷酸二乙酯 Diethyl 2-Bromoethylphosphonate 25G 1220元 2010/06/21 114180250 2-溴乙基膦酸二乙酯 Diethyl 2-bromoethylphosphonate 97% 25 GR 1420元
  • 2-溴乙基膦酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1781 2-溴乙基磷酸二乙酯 Diethyl 2-Bromoethylphosphonate 5G 435元 2014/06/02 B1781 2-溴乙基磷酸二乙酯 Diethyl 2-Bromoethylphosphonate 25G 1230元 2010/06/21 114180250 2-溴乙基膦酸二乙酯 Diethyl 2-bromoethylphosphonate 97% 25 GR 1420元
  • Sigma Aldrich:5324-30-1(sigmaaldrich)
  • Alfa Aesar:2-溴乙基磷酸二乙酯,97% Diethyl 2-bromoethylphosphonate, 97%(5324-30-1)
  • MOL 文件:5324-30-1.mol
  • 图谱信息:2-溴乙基膦酸二乙酯(5324-30-1)核磁图( 13 CNMR) 2-溴乙基膦酸二乙酯(5324-30-1)红外图谱(IR1) 2-溴乙基膦酸二乙酯(5324-30-1)核磁图( 1 HNMR) 2-溴乙基膦酸二乙酯(5324-30-1)质谱(MS)
  • Acros Organics:2-溴乙基磷酸二乙酯 Diethyl 2-bromoethylphosphonate, 97%(5324-30-1)
  • TCI Shanghai:2-溴乙基磷酸二乙酯 Diethyl 2-Bromoethylphosphonate,>;95.0%(GC)(5324-30-1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction

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