Bis(Perfluorophenyl)(Phenyl)Phosphine 双(五氟苯基)苯膦

CAS 5074-71-5 MFCD00000291

化学结构图

5074-71-5
SMILES: Fc1c(F)c(F)c(P(c2ccccc2)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

化学属性

TSCANo
Mol. FormulaC18H5F10P
Mol. Weight442.19
Flash Point>110°C
Appearance white pwdr.
Stabilityair sensitive
Boiling Point105 °C at 0.3 mmHg
Melting Point55-60 °C

别名和识别编码

Chemical NameBis(Perfluorophenyl)(Phenyl)Phosphine
Synonym Decafluorotriphenylphosphine {LY} Decafluorotriphenylphosphine {} {LY} Decafluorotriphenylphosphine {} {} {LY} Decafluorotriphenylphosphine {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Decafluorotriphenylphosphine {} {} {} {} {} {} {}
PubChem Substance ID253662383
EC Number225-780-1
Beilstein Registry Number6253897
MDL NumberMFCD00000291
Chemical Name Translation双(五氟苯基)苯膦
Reaxys-RN949443
InChIKeyOYNXPGGNQMSMTR-UHFFFAOYSA-N
LabNetwork Molecule IDLN01740871
CAS Number5074-71-5
Canonical SMILESFC1=C(C(P(C2=CC=CC=C2)C3=C(C(F)=C(C(F)=C3F)F)F)=C(C(F)=C1F)F)F
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分类

  • {SNA} Additional Standards, Analytical Standards, MS Markers, MS Standards, Organic Pollutant Standards, Perfluoro Compounds, Physical Properties Standards, Single Compounds, Spectroscopy, 分析/色谱
  • {SNA} Analytical Standards, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy, 分析/色谱
  • {SNA} Analytical Standards,
  • {SA} Analytical Standards, Analytical/Chromatography, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy
  • 600 Series Wastewater Methods, 8000 Series Solidwaste Methods,

相关文献及参考

  • FT-IR 1 (2), 543:C / FT-IR 2 (2), 3317:D / FT-NMR 1 (2), 1657:B / IR-Spectra (3), 1182:H / NMR-Reference 2 (2), 879:A / RegBook 1 (2), 2265:F / Structure Index 1 , 354:B:8

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi,Xn,T,F Xi
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
UN Number UN 1593 6.1/PG 3

其他信息

  • Alfa Aesar:双(五氟苯基)苯膦,97% Bis(pentafluorophenyl)phenylphosphine, 97%(5074-71-5)
  • Sigma Aldrich:5074-71-5(sigmaaldrich)
  • Acros Organics:十氟三苯基磷 Bis(pentafluorophenyl)phenylphosphine, tech., 90%(5074-71-5)
  • 十氟三苯基磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 313171000 十氟三苯基磷 Bis(pentafluorophenyl)phenylphosphine 90%, tech. 100 MG 549元 2010/05/25 A11014 双(五氟苯基)苯膦,97% Bis(pentafluorophenyl)phenylphosphine, 97% 250mg 692元 2010/05/25 A11014 双(五氟苯基)苯膦,97% Bis(pentafluorophenyl)phenylphosphine, 97% 1g 2212元
  • Hazard Note:Irritant
  • MOL 文件:5074-71-5.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DA - DH - D
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Physical Properties - Analytical Standards
  4. MS Standards - Physical Properties
  5. Single Compounds - MS Standards
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Phosphines

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