2-Fluorobenzyl bromide 邻氟溴苄

CAS 446-48-0 MFCD00000324

化学结构图

446-48-0
SMILES: Fc1ccccc1CBr

化学属性

Mol. FormulaC7H6BrF
Mol. Weight189
Boiling Point115°C/50mmHg(lit.)
Density1.567 g/mL at 25 °C(lit.)
Refractive index1.5490 to 1.5530
Flash Point82°C(lit.)
TSCANo
Stability对光线和湿度敏感
Appearance 无色液体
pH:A

别名和识别编码

Chemical Name2-Fluorobenzyl bromide
CAS Number446-48-0
Alfabeta NameFLUOROBENZYLBROMIDE 2-
MDL NumberMFCD00000324
EC Number207-169-1
Beilstein Registry Number5(2)238
Synonym 2-氟苄基溴 -Bromo-2-fluorotoluene O-FLUOROBENZYL BROMIDE 2-氟苄溴 2-氟苯甲基溴 2-fluoro(bromomethyl)benzene ALPHA-BROMO-2-FLUOROTOLUENE α-Bromo-2-fluorotoluene 2-氟苄基溴，邻氟溴苄，2-氟溴苄 2-氟溴苄 ALPHA-BROMO-O-FLUOROTOLUENE 邻氟溴苄 2-Fluorobenzylbromide,98% 2-FLUOROBENZYL BROMIDE alpha-Bromo-o-fluorotoluene 1-(BROMOMETHYL)-2-FLUORO-BENZENE 2-FLUOROBENZYL BROMIDE 98% Benzene, 1-(bromomethyl)-2-fluoro- alpha-Bromo-2-fluorotoluene
PubChem Substance ID67968
Chemical Name Translation邻氟溴苄
Reaxys-RN1099894
InChIKeyFFWQLZFIMNTUCZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115415
InChIInChI=1S/C7H6BrF/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C7, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Beilstein:5(2)238

安全信息

Warnings LACHRYMATOR, CORROSIVE
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number UN3265 3265
Hazard Codes C
Storage condition 对湿度和光线敏感，密封避光保存。
Hazard Class8

其他信息

  • Sigma Aldrich:446-48-0(sigmaaldrich)
  • 存储注意事项:湿度敏感;氮气保护
  • 检测方法:GC
  • 2-氟溴苄价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010163 2-氟溴苄 25g 200元 2011/04/16 F0209 2-氟苄溴 2-Fluorobenzyl Bromide 5G 551元 2011/04/16 F0209 2-氟苄溴 2-Fluorobenzyl Bromide 25G 1440元
  • Hazard Note:Corrosive/Lachrymatory
  • 下游产品:邻氟苯乙酸乙酯 --> 2-氟苯基甲磺酰氯
  • MSDS 信息:2-Fluorobenzyl bromide(446-48-0).msds
  • Acros Organics:2-氟苄溴 2-Fluorobenzyl bromide, 98%(446-48-0)
  • MOL 文件:446-48-0.mol
  • 图谱信息:2-氟溴苄(446-48-0)红外图谱(IR1) 2-氟溴苄(446-48-0)质谱(MS)
  • TCI Shanghai:2-氟苄溴 2-Fluorobenzyl Bromide,>;95.0%(GC)(446-48-0)
  • Alfa Aesar:2-氟苯甲基溴,98% 2-Fluorobenzyl bromide, 98%(446-48-0)
  • 敏感性:Lachrymatory

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C7 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C6

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