Benzoyl Fluoride 苯甲酰氟
CAS 455-32-3 MFCD00000364
化学结构图
SMILES: O=C(F)c1ccccc1
化学属性
| Mol. Formula | C7H5FO |
|---|---|
| Mol. Weight | 124 |
| Boiling Point | 160°C |
| Melting Point | -28° |
| TSCA | T |
| Density | 1.140 |
| Refractive index | 1.4930 to 1.5030 |
| Flash Point | 49°C(lit.) |
别名和识别编码
| Chemical Name | Benzoyl Fluoride |
|---|---|
| CAS Number | 455-32-3 |
| Alfabeta Name | BENZOYLFLUORIDE |
| MDL Number | MFCD00000364 |
| Synonym | {uni_hamburg} Benzoyl fluoride 99% Benzoic acid, fluoride BENZOYL FLUORIDE 苯甲酰氟 Benzoylfluoride99% Benzoylfluorid Benzoic acid fluoride 苯甲醯氟 苯酰氟 benzoyl fluoride |
| EC Number | 207-244-9 |
| Beilstein Registry Number | 9,181 |
| PubChem Substance ID | 67999 |
| Chemical Name Translation | 苯甲酰氟 |
| Reaxys-RN | 1904977 |
| InChI | InChI=1S/C7H5FO/c8-7(9)6-4-2-1-3-5-6/h1-5H |
| LabNetwork Molecule ID | LN00116411 |
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbonyl fluoride; 1fragment
- {SNA} Acid Halides, Aryl Fluorinated Building Blocks, Building Blocks, C7, Carbonyl Compounds, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
相关文献及参考
- Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
- Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19c Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54893-9 ISBN: 978-3-540-54893-5 Internet Resource: DOI:10.1007/b44435 RefComment: 8 figs., XI, 295 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplem
安全信息
- R10 Flammable 易燃
- R34 Causes burns 会导致灼伤
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P234 Keep only in original container. 只保留在原来的容器中。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P403+P235
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
其他信息
- MOL 文件:455-32-3.mol
- Hazard Note:Highly Toxic/Lachrymator
- Sigma Aldrich:455-32-3(sigmaaldrich)
- TSCA:T
- Alfa Aesar:苯甲酰氟,98% Benzoyl fluoride, 98%(455-32-3)
- 下游产品:邻氟苯甲酸
- TCI Shanghai:苯甲酰氟 Benzoyl Fluoride,>;95.0%(T)(455-32-3)
- 图谱信息:苯甲酰氟(455-32-3)红外图谱(IR1)
- 苯甲酰氟价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1115 苯甲酰氟 Benzoyl Fluoride 5G 260元 2014/06/02 B1115 苯甲酰氟 Benzoyl Fluoride 25G 883元 2010/05/25 L11464 苯甲酰氟, 98% Benzoyl fluoride, 98% 5g 192元
- 敏感性:Lachrymatory
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