1,2-Dibromotetrafluoroethane 1,2-二溴四氟乙烷

CAS 124-73-2 MFCD00000368

化学结构图

124-73-2
SMILES: FC(F)(Br)C(F)(F)Br

化学属性

Mol. FormulaC2Br2F4
Mol. Weight259.82
Appearance 无色透明液体。熔点-112℃,沸点46.4℃,相对密度2.149(25/4℃),折光率1.361(25℃)。
Boiling Point47,3°C
Melting Point-110,5°C
Refractive index1.347
Density2,175 g/cm3
Flash Point-16.4±18.4 °C
Danger-Level甲类

别名和识别编码

Chemical Name1,2-Dibromotetrafluoroethane
Synonym 1,2-DibroMotetrafluoroethane {LY} 1,2-DibroMotetrafluoroethane {} {LY} 1,2-DibroMotetrafluoroethane {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-DibroMotetrafluoroethane
EC Number204-711-9
CAS Number124-73-2
MDL NumberMFCD00000368
Chemical Name Translation1,2-二溴四氟乙烷
Wiswesser Line NotationFXFEXFFE
Beilstein Registry Number1740342
LabNetwork Molecule IDLN00009711
PubChem Substance ID31301
InChIInChI=1S/C2Br2F4/c3-1(5,6)2(4,7)8
Canonical SMILESBrC(F)(F)C(F)(F)Br
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分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. E

安全信息

Packing GroupIII
Hazard Codes Xi
Hazard Class6.1(b)
UN Number 3082
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R59 Dangerous for the ozone layer 对臭氧层有危害
RTECSKH9370300
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 gm/m3/2H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   TLSMA6 Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo
   Instituta.  (Leningrad, Russia) V.1-145, 1949-82.  Discontinued.
   Volume(issue)/page/year: 75,241,1963

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 584 gm/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571410

Hazard statements
  • H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere 通过破坏上层大气臭氧层而危害公众健康和环境。
Precautionary statements
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • MOL 文件:124-73-2.mol
  • 上游原料:溴 --> 四氟乙烯 --> 工业溴
  • 用途一:可作高效灭火剂、冷却剂、高温气体润滑剂,也用作传热介质等。
  • Hazard Note:Irritant
  • 下游产品:1-苯基-5-三氟甲基-1H-吡唑-4-醛 --> 1-苯基-5-三氟甲基-4-溴-1H-吡唑
  • 方法一:由四氟乙烯经溴素加成而得。四氟乙烯经两次加成反应后,经冷凝、中和、精馏,再经分离去低沸点物,即得成品。工业品纯度≥99.5%。原料消耗定额:四氟乙烯(80%)525kg/t、工业溴1000kg/t。

系列性分类


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