五氟丙酸乙酯 五氟丙酸乙酯

CAS 426-65-3 MFCD00000431

化学结构图

426-65-3
SMILES: CCOC(=O)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC5H5F5O2
Mol. Weight192.09
Boiling Point75.5°C at 760mmHg
TSCAT
Refractive index1.2290 to 1.3030
Density1.299
Flash Point1.67°C
Melting Point75.5 °C

别名和识别编码

Chemical Name五氟丙酸乙酯
CAS Number426-65-3
Alfabeta NameETHYLPENTAFLUOROPROPIONATE
MDL NumberMFCD00000431
PubChem Substance ID67928
EC Number207-043-6
Beilstein Registry Number1779789
Reaxys-RN1779789
Synonym Ethyl 2,2,3,3,3-pentafluoropropanoate {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoropropanoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2,2,3,3,3-pentafluoroprop
Chemical Name Translation五氟丙酸乙酯
InChIKeyDBOFMRQAMAZKQY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00118968
InChIInChI=1S/C5H5F5O2/c1-2-12-3(11)4(6,7)5(8,9)10/h2H2,1H3
Canonical SMILESO=C(OCC)C(F)(F)C(F)(F)F
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分类

  • Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SNA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Perfluoroalkyl carboxylate esters undergo Wittig reactions with phosphorus ylides, leading to 1-perfluoroalkyl enol ethers, which are useful precursors of various fluorinated derivatives: J. Org. Chem., 57, 3807 (1992); Org. Synth., 75, 153 (1997). See Ethyl­ trifluoroacetate, A11520, for reaction scheme.

安全信息

Warnings IRRITANT, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard Codes 3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3272
Packing GroupII
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 五氟丙酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P1123 五氟丙酸乙酯 Ethyl Pentafluoropropionate 5G 297元 2011/04/16 P1123 五氟丙酸乙酯 Ethyl Pentafluoropropionate 25G 857元 2010/05/25 L01782 五氟丙酸乙酯, 98+% Ethyl pentafluoropropionate, 98+% 5g 210元
  • MOL 文件:426-65-3.mol
  • Hazard Note:Flammable
  • Sigma Aldrich:426-65-3(sigmaaldrich)
  • TSCA:T
  • 五氟丙酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1123 五氟丙酸乙酯 Ethyl Pentafluoropropionate 5G 292元 2014/06/02 P1123 五氟丙酸乙酯 Ethyl Pentafluoropropionate 25G 850元 2010/05/25 L01782 五氟丙酸乙酯, 98+% Ethyl pentafluoropropionate, 98+% 5g 210元
  • 图谱信息:五氟丙酸乙酯(426-65-3)核磁图( 1 HNMR) 五氟丙酸乙酯(426-65-3)核磁图( 13 CNMR) 五氟丙酸乙酯(426-65-3)红外图谱(IR1) 五氟丙酸乙酯(426-65-3)质谱(MS)
  • Alfa Aesar:五氟丙酸乙酯,98+% Ethyl pentafluoropropionate, 98+%(426-65-3)
  • TCI Shanghai:五氟丙酸乙酯 Ethyl Pentafluoropropionate,>;98.0%(GC)(426-65-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C2 to C5 - Esters
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学

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