Heptafluorobutyric anhydride 七氟丁酸酐

CAS 336-59-4 MFCD00000432

化学结构图

336-59-4
SMILES: O=C(OC(=O)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC8F14O3
Mol. Weight410.06
Boiling Point108-110 °C at 760 mmHg
TSCAT
Density1.674
Refractive indexn20/D 1.287(lit.)
Melting Point-43 °C
Solubility起反应
Flash PointNone
Stability对湿度敏感

别名和识别编码

Chemical NameHeptafluorobutyric anhydride
CAS Number336-59-4
Alfabeta NameHEPTAFLUOROBUTYRICANHYDRIDE
MDL NumberMFCD00000432
Synonym Perfluorobutyric anhydride {LY} Perfluorobutyric anhydride {} {LY} Perfluorobutyric anhydride {} {} {LY} Perfluorobutyric anhydride {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyr
EC Number206-410-8
Beilstein Registry Number856036
PubChem Substance ID67643
Reaxys-RN856036
Chemical Name Translation七氟丁酸酐
InChIKeyUFFSXJKVKBQEHC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115757
InChIInChI=1S/C8F14O3/c9-3(10,5(13,14)7(17,18)19)1(23)25-2(24)4(11,12)6(15,16)8(20,21)22
Canonical SMILESO=C(OC(C(F)(F)C(F)(F)C(F)(F)F)=O)C(F)(F)C(F)(F)C(F)(F)F
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; carbo-anhydride; 1fragment
  • {SNA} β-Glucuronidase, β-Glucuronidase Drug Analysis Bundle, Ac
  • {SA} β-Glucuronidase, β-Glucuronidase Drug Analysis Bundle, Alkyl Fluorinated Building Blocks, Analytical and Industrial Enzymes, Biochemicals and Reagents,

产品应用

  • GC-MS 分析合成肽立体异构体含量的衍生化试剂。
  • GC 衍生化试剂，用于制备氨基酸和其他生物活性化合物的挥?发性衍生物

相关文献及参考

  • Reagent for the preparation of volatile heptafluorobutyryl derivatives of amines, alcohols, etc., for GC purposes: J. Chromat., 60, 134 (1971); 69, 157 (1972); 97, 19, 175 (1974); D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); Handbook of Derivatives for Chromatography, 2nd ed., K. Blau and J. M. Halket, Eds., Wiley, Chichester (1993).
  • Short: II/27B
  • Short: EINECS
  • Reagent for the preparation of volatile heptafluorobutyryl derivatives of amines, alcohols, etc., for GC purposes: J. Chromat., 60, 134 (1971); 69, 157 (1972); 97, 19, 175 (1974); D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); H
  • Beilstein:2(4)817

安全信息

Warnings MOISTURE SENSITIVE, HYGROSCOPIC, CORROSIVE
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Storage condition -20°C, sealed storage, away from moisture {LY} -20°C, sealed storage, away from moisture 2-8°C Moisture Sensitive Room temp {} {LY} -20°C, sealed storage, away from moisture {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moistu
Hazard Codes 8 C
Hazard Class8

其他信息

  • Sigma Aldrich:336-59-4(sigmaaldrich)
  • Hazard Note:Corrosive/Hygroscopic
  • 上游原料:五氧化二磷 --> 七氟丁酸
  • 检测方法:GC,NMR,MS
  • TSCA:T
  • MSDS 信息:Perfluorobutyric anhydride(336-59-4).msds
  • 存储注意事项:湿度敏感
  • TCI Shanghai:七氟丁酸酐 Heptafluorobutyric Anhydride,>;95.0%(T)(336-59-4)
  • 七氟丁酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0337 七氟丁酸酐 Heptafluorobutyric Anhydride 10G 656元 2010/06/21 169260250 七氟丁酸酐 Heptafluorobutyric anhydride 98+% 25 GR 1754元 2010/06/21 169260050 七氟丁酸酐 Heptafluorobutyric anhydride 98+% 5 GR 501元
  • 图谱信息:七氟丁酸酐(336-59-4)红外图谱(IR1) 七氟丁酸酐(336-59-4)质谱(MS)
  • Alfa Aesar:七氟丁酸酐,98% Heptafluorobutyric anhydride, 98%(336-59-4)
  • 敏感性:Hygroscopic
  • Acros Organics:七氟丁酸酐 Heptafluorobutyric anhydride, 98+%(336-59-4)
  • F:10-21
  • MOL 文件:336-59-4.mol
  • 用途一:气相色谱中的衍生化试剂、酰化试剂。
  • 和水反应形成丁酸。
  • 海关编码:29159080

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Acylation - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Trifluoromethyl 三氟甲基
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Analytical Enzymes - Enzymes, Inhibitors, and Substrates
  5. β-Glucuronidase - Analytical Enzymes
  6. β-Glucuronidase Drug Analysis Bundle - β-Glucuronidase
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents GC
  4. GC Derivatization Reagents, by Application
  5. Steroids
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Derivatization Reagents
  4. GC Derivatization Reagents, by Application
  5. Steroids

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