Ethyl 2,2,3,3,4,4,4-Heptafluorobutanoate 2,2,3,3,4,4,4-七氟丁酸乙酯

CAS 356-27-4 MFCD00000434

化学结构图

356-27-4
SMILES: CCOC(=O)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaCF3CF2CF2CO2CH2CH3
Mol. Weight242
Refractive index1.3010 to 1.3050
Density1.396
Flash Point14°C(lit.)
TSCAYes
Boiling Point96°C(lit.)

别名和识别编码

Chemical NameEthyl 2,2,3,3,4,4,4-Heptafluorobutanoate
Synonym Ethyl heptafluorobutanoate Perfluorobutyric Acid Ethyl Ester HEPTAFLUORO-N-BUTYRIC ACID ETHYL ESTER heptafluoro-butyricaciethylester TIMTEC-BB SBB008806 Ethyl perfluorobutyrate heptafluoro-butyric acid ethyl ester ethylperfluorobutanoate ethylheptafluorobutanoate 七氟丁酸乙酯 庚氟丁酸乙酯
CAS Number356-27-4
PubChem Substance ID9644
EC Number206-602-1
Beilstein Registry Number1794634
MDL NumberMFCD00000434
Reaxys-RN1794634
Chemical Name Translation2,2,3,3,4,4,4-七氟丁酸乙酯
Wiswesser Line NotationFXFFXFFXFFVO2
InChIKeyJVHJRIQPDBCRRE-UHFFFAOYSA-N
LabNetwork Molecule IDLN01742573
InChIInChI=1S/C6H5F7O2/c1-2-15-3(14)4(7,8)5(9,10)6(11,12)13/h2H2,1H3
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • Short: II/27B
  • Perfluoroalkyl carboxylate esters undergo Wittig reactions with phosphorus ylides, leading to 1-perfluoroalkyl enol ethers, which are useful precursors of various fluorinated derivatives: J. Org. Chem., 57, 3807 (1992); Org. Synth., 75, 153 (1997). See Ethyl­ trifluoroacetate, A11520, for reaction scheme.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,Xi
RTECSET4200000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338+P337+P313
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P241+P242+P243
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
Signal word
Safety Statements
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number
Packing GroupII
Hazard Class3
Storage condition Flammables area 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,299,1950

其他信息

  • 庚氟丁酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0594 七氟丁酸乙酯 Ethyl Heptafluorobutyrate 5G 234元 2014/06/02 H0594 七氟丁酸乙酯 Ethyl Heptafluorobutyrate 25G 669元 2010/06/21 174440250 庚氟丁酸乙酯 Ethyl heptafluorobutyrate 97% 25 GR 936元
  • Acros Organics:Ethyl heptafluorobutyrate, 97%(356-27-4)
  • TSCA:T
  • TCI Shanghai:七氟丁酸乙酯 Ethyl Heptafluorobutyrate,>;97.0%(GC)(356-27-4)
  • Alfa Aesar:七氟丁酸乙酯,98% Ethyl heptafluorobutyrate, 98%(356-27-4)
  • Hazard Note:Highly Flammable
  • Sigma Aldrich:356-27-4(sigmaaldrich)
  • 图谱信息:庚氟丁酸乙酯(356-27-4)红外图谱(IR1) 庚氟丁酸乙酯(356-27-4)质谱(MS) 庚氟丁酸乙酯(356-27-4)Raman光谱 庚氟丁酸乙酯(356-27-4)核磁图( 1 HNMR)
  • MOL 文件:356-27-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C6 to C7 - Esters

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