Perfluorotributylamine 二十七氟三丁基胺

CAS 311-89-7 MFCD00000436

化学结构图

311-89-7
SMILES: FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC12F27N
Mol. Weight671.10
Boiling Point178
TSCAY
Density1.883
Refractive index1.2890
Melting Point-52 °C
Vapor Density23.3 (vs air)
Vapor Pressure1.3 mmHg ( 25 °C)
Solubility不溶
Flash PointNone
Appearance liquid 全氟三丁胺(311-89-7)为无色液体。熔点-66℃，沸点177℃，相对密度1.872（25/4℃），折光率1.2910（25℃）。溶于丙酮。是一种惰性液体。

别名和识别编码

Chemical NamePerfluorotributylamine
CAS Number311-89-7
Alfabeta NamePERFLUOROTRIBUTYLAMINE N--
MDL NumberMFCD00000436
Synonym Perfluorotributylamine {LY} Perfluorotributylamine {} {LY} Perfluorotributylamine {} {} {LY} Perfluorotributylamine {} {} {} {LY} Perfluorotributylamine {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorotributylamine
PubChem Substance ID125309938
EC Number206-223-1
Beilstein Registry Number2(4)819
Reaxys-RN1813883
Chemical Name Translation二十七氟三丁基胺
LabNetwork Molecule IDLN00119252
InChIInChI=1S/C12F27N/c13-1(14,7(25,26)27)4(19,20)10(34,35)40(11(36,37)5(21,22)2(15,16)8(28,29)30)12(38,39)6(23,24)3(17,18)9(31,32)33
Canonical SMILESFC(N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(F)C(F)(F)C(F)(F)C(F)(F)F
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分类

  • {SNA} Alphabetic, Analytical Standards, Analytical/Chromatography, H, HA -HT, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy
  • {SA} Alphabetic, Analytical Standards, Analytical/Chromatography, H, HA -HT, MS Markers, MS Standards, Physical Properties, Single Compounds, Spectroscopy
  • {SNA} Additional Standards, Analytical Standards, MS Markers, MS Standards, Organic Pollutant Standards, Perfluoro Compounds, Physical P

相关文献及参考

  • Short: II/27B
  • Short: II/5
  • Standard for use in mass spectrometry.
  • Short: III/38B

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi Xi,T
RTECSYA1000000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0533842

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 12 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MIVRA6 Microvascular Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1968-  Volume(issue)/page/year: 8,320,1974

其他信息

  • 图谱信息:全氟三丁胺(311-89-7)质谱(MS) 全氟三丁胺(311-89-7)红外图谱(IR2) 全氟三丁胺(311-89-7)红外图谱(IR1)
  • 全氟三丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 P0074 全氟三丁胺[用于质谱法] Heptacosafluorotributylamine [for Mass spectrometry] 25G 780元 2010/06/21 123772500 全氟三丁胺 Perfluoro-compound FC-43™ 250 GR 8453元 2010/06/21 123770100 全氟三丁胺 Perfluoro-compound FC-43™ 10 GR 533元
  • 全氟三丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0074 全氟三丁胺[用于质谱法] Heptacosafluorotributylamine [for Mass spectrometry] 25G 350元 2010/06/21 123772500 全氟三丁胺 Perfluoro-compound FC-43™ 250 GR 8453元 2010/06/21 123770100 全氟三丁胺 Perfluoro-compound FC-43™ 10 GR 533元
  • Alfa Aesar:全氟三正丁胺,tech.90% Perfluorotri-n-butylamine, tech. 90%(311-89-7)
  • 用途二:该品对热和化学稳定性好，有良好的润滑性和耐磨性、优良的介电性能和耐腐蚀性能，可用作仪表隔离液、导热冷却剂，在高频系统的无件中作为绝缘介质，利用其表面张力小的特点，可用作石油破乳剂。还可与四氟乙烯混合制备氟酯。
  • 蒸气密度:23.3 (vs air)
  • 方法一:由三丁胺与氟化氢通过电解氟化而得。电解产物经水洗、碱洗、干燥、精馏而得成品。
  • 用途一:导热热冷却剂
  • 上游原料:三正丁胺
  • MOL 文件:311-89-7.mol
  • 凝固点:-60℃
  • 蒸气压:1.3 mm Hg ( 25 °C)
  • Acros Organics:全氟三丁胺 Perfluoro-compound FC-43?(311-89-7)
  • Sigma Aldrich:311-89-7(sigmaaldrich)
  • MSDS 信息:Heptacosafluorotributylamine(311-89-7).msds
  • TSCA:T

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. EPA - Method Specific
  5. 600 Series Wastewater Methods - EPA
  6. Method 625 - 600 Series Wastewater Methods
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. H - Alphabetic
  5. HA -HT - H
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Physical Properties - Analytical Standards
  4. MS Standards - Physical Properties
  5. Single Compounds - MS Standards
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Analytical & Chromatography 分析化学与色谱
  2. Mass Spectrometry
  1. Organo Fluorine
  2. Fluorine
  1. Ligands
  2. Fluorine 氟配体

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