Benzylmagnesium Chloride 苄基氯化镁

CAS 6921-34-2 MFCD00000469

化学结构图

6921-34-2
SMILES: Cl[Mg]Cc1ccccc1

化学属性

TSCAYes
Solubility剧烈反应
Flash Point1°F (THF)
Appearance liq.
Stabilityair sensitive, moisture sensitive
Density1.03
Mol. FormulaC7H7ClMg
Mol. Weight150.89
RedoxReduction

别名和识别编码

Chemical NameBenzylmagnesium Chloride
Synonym Benzylmagnesium chloride,1.0M solution in THF,Safeseal {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} { {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {LY} Benzylmagnesium chloride,1.0M solution in THF,Safes
EC Number230-039-0
Beilstein Registry Number16(4)1690
PubChem Substance ID2733352
Reaxys-RN6119156
Chemical Name Translation苄基氯化镁
InChIKeyNRAFPLGJPPJUNB-UHFFFAOYSA-M
InChIInChI=1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q-1;;+2/p-1
MDL NumberMFCD00000469
CAS Number6921-34-2
Canonical SMILES[CH2-]C1=CC=CC=C1.[Mg+2].[Cl-]
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分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Organometallic Reagents
  • {SNA} 12 Principles Aligned Products, 25mL Sure/Seal Reagents, Chemical Synthesis, Greener Alternative Products, Organometalics, Organometallic Reagents
  • {uni_hamburg} no charge; metal-organic; carbocycle; aromatic;

相关文献及参考

  • Beilstein:16(4)1690
  • Short: EINECS
  • Short: III/35D5

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S8 Keep container dry 保持容器干燥；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 2924 UN2924
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture water-free area {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed st
Hazard Codes 3 F+,C
Hazard Class3/8

其他信息

  • Acros Organics:苄基氯化镁 (20% 四氢呋喃) Benzylmagnesium chloride, 1.4M solution in THF, AcroSeal?(6921-34-2)
  • Sigma Aldrich:6921-34-2(sigmaaldrich)
  • TCI Shanghai:苄基氯化镁(16%的四氢呋喃溶液,约1mol/L) Benzylmagnesium Chloride (ca. 16% in Tetrahydrofuran, ca. 1mol/L)(6921-34-2)
  • 苄基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 XW69213421 苄基氯化镁 100ml 298元 2011/08/23 XW69213422 苄基氯化镁 500ml 698元 2011/04/16 B1933 苄基氯化镁(约16%的四氢呋喃溶液,约1mol/L) Benzylmagnesium Chloride (ca. 16% in Tetrahydrofuran, ca. 1mol/L) 250G 1880元
  • MOL 文件:6921-34-2.mol
  • Alfa Aesar:Benzylmagnesium chloride, 1-2M in THF(6921-34-2)
  • F:1-3-10
  • 敏感性:Air & Moisture Sensitive
  • 下游产品:二甲基苄基原醇 --> 戊基苯 --> 苄基硼酸

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Potable- & Waste-Water Testing - Analytical Reagents
  4. Replacement Kit Items - Potable- & Waste-Water Testing
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl
  1. Functional Group 官能团索引
  2. organomagnesium compound
  1. Grignard
  2. Magnesium

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