Isobutylmagnesium chloride 异丁基氯化镁

CAS 5674-02-2 MFCD00000471

化学结构图

5674-02-2
SMILES: CC(C)C[Mg]Cl

化学属性

Mol. FormulaC4H9ClMg
Mol. Weight117
Density0.967
Boiling Point65-67
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameIsobutylmagnesium chloride
CAS Number5674-02-2
EC Number250-023-7
Beilstein Registry Number3535133
MDL NumberMFCD00000471
PubChem Substance ID4384856
Synonym Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} Isobutyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {LY} Isobutyl magnesium chloride
Chemical Name Translation异丁基氯化镁
InChIKeyYUPZOKFCNKSJTR-UHFFFAOYSA-M
LabNetwork Molecule IDLN01314137
InChIInChI=1S/C4H9.ClH.Mg/c1-4(2)3;;/h4H,1H2,2-3H3;1H;/q-1;;+2/p-1
Canonical SMILESCl[Mg]CC(C)C
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分类

  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P370+P378
  • P402+P404
  • P403+P235
  • P422 Store contents under… 存储目录在…之下。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F,C F,Xn
Packing GroupI
UN Number 3399
Restrict -
Storage condition

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Functional Group 官能团索引
  2. organomagnesium compound

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