Propylmagnesium Chloride 丙基氯化镁

CAS 2234-82-4 MFCD00000474

化学结构图

2234-82-4
SMILES: [CH2-]CC.[Cl-].[Mg+2]

化学属性

Mol. FormulaC3H7ClMg
Mol. Weight102.85
Density0.827
TSCAYes
Stability对湿度、空气敏感

别名和识别编码

Chemical NamePropylmagnesium Chloride
CAS Number2234-82-4
EC Number250-023-7
Beilstein Registry Number3600246
MDL NumberMFCD00000474
PubChem Substance ID75225
Synonym 丙基氯化镁 丙基氯化镁 溶液 正-丙基氯化镁
Chemical Name Translation丙基氯化镁
LabNetwork Molecule IDLN01358337
InChIInChI=1S/C3H7.ClH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q-1;;+2/p-1
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分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Grignard Reagents, Organometa
  • {SNA} 12 Principles Aligned Products, 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Greener Alternative Products, Grignard Reagents, Organometalics, Organometallic Reagents
  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents

产品应用

  • Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

安全信息

Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Risk Statements
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C
Packing GroupI
UN Number
Storage condition Air & Moisture Sensitive 充氩保存

其他信息

  • 和水剧烈反应

系列性分类


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