Ethyltrichlorosilane 三氯乙基硅烷

CAS 115-21-9 MFCD00000485

化学结构图

115-21-9
SMILES: CC[Si](Cl)(Cl)Cl

化学属性

Mol. FormulaC2H5Cl3Si
Mol. Weight164
Refractive index1.4230 to 1.4270
Boiling Point100°C
Density1.238 g/mL at 25 °C(lit.)
Melting Point-106 °C(lit.)
Flash Point14°C(lit.)
Solubility溶于苯、乙醚、卤代烃等多数有机溶剂。

别名和识别编码

Chemical NameEthyltrichlorosilane
MDL NumberMFCD00000485
CAS Number115-21-9
Synonym trichloro-ethyl-silane 三氯乙基硅烷 ATC Ethyl trichlorosilane trichloro(ethyl)silane Silicane, trichloroethyl- 乙基三氯矽烷 Trichloroethylsilicane C2H5SiCl3 ETHYL SILICONE TRICHLORIDE ETHYLTRICHLOROSILANE Ethyl silicon trichloride Ethyltrichlorosilane,98% 乙基三氯化硅 ethyl-trichloro-silane ethyltrichloro-silan ethyltrichlorosilane Trichloroethylsilane trichloroethyl-silan Silane, ethyltrichloro- trichloroethylsilicon dow corning product z-1212 CE6350 ethylsilicontrichloride silane, trichloroethyl- ethyl silicon trichloride Trichlorethylsilan Ethyltrichlorsilan Dow Corning® 产品 Z-1212 三氯乙基硅烷 Silane, trichloroethyl- Trichloro(ethyl)silane trichloroethylsilane Trichloroethylsilane: (Ethyl trichlorosilane) ETHYLTRICHLOROSILANE, 98+%, DEPOSITION & TRICHLOROETHYLSILICANE ethyl(trichloro)-silan TRICHLOROETHYLSILANE 乙基三氯硅烷 trichloroethyl-silican
PubChem Substance ID87569478
EC Number204-072-6
Beilstein Registry Number4(3)1900
Chemical Name Translation三氯乙基硅烷
Reaxys-RN1361384
Wiswesser Line NotationG-SI-GG2
LabNetwork Molecule IDLN01281449
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分类

  • {SNA} Materials Science, Micro/NanoElectronics, Nanomaterials, POSS Precursors and Intermediates, RSiCl3, Self Assembly & Contact Printing, Silane Coupling Agents/Adhesion Promoters, Silsesquioxanes: POSS Nanohybrids, Trichlorosilanes
  • {SNA} Chemical Synthesis, Micro/NanoElectronics, Protecting and Derivatizing Reagents, Protection and Derivatization, Silanes, Silicon, Silicon-Based, Solution Deposition Precursors, Synthetic Reagents, 材料科学
  • {uni_hamburg} no charge; 1fragment
  • {SA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Protecting and Derivatizing Reagents, Protection and Derivatization,

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure
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安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV4200000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
Hazard Codes F,C F,T+
Hazard Class3/8
UN Number 1196 UN 1196 3/PG 2
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R26 Very toxic by inhalation 吸入极毒
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R11 Highly flammable 非常易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R37 Irritating to respiratory system 刺激呼吸道
  • R35 Causes severe burns 会导致严重灼伤
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1330 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,343,1949

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 3,23,1961

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 30,332,1948

其他信息

  • 图谱信息:乙基三氯硅烷(115-21-9)红外图谱(IR1) 乙基三氯硅烷(115-21-9)质谱(MS) 乙基三氯硅烷(115-21-9)核磁图( 1 HNMR) 乙基三氯硅烷(115-21-9)核磁图( 13 CNMR)
  • 灭火剂:干粉、干砂、干石粉、二氧化碳
  • Sigma Aldrich:115-21-9(sigmaaldrich)
  • 毒性分级:中毒
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 高热分解有毒光气; 遇水放出氯化物毒雾
  • 刺激数据:皮腹- 兔子 500 毫克/ 24小时 轻度; 眼- 兔子 0.25 毫克/ 24小时 重度
  • TCI Shanghai:三氯乙基硅烷 Ethyltrichlorosilane,>;98.0%(T)(115-21-9)
  • 急性毒性:口服- 大鼠 LD50: 1330 毫克/ 公斤; 吸入- 大鼠: 500 PPM/ 4 小时
  • 类别:易燃液体
  • 乙基三氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0188 三氯乙基硅烷 Ethyltrichlorosilane 500G 1280元 2014/06/02 E0188 三氯乙基硅烷 Ethyltrichlorosilane 25G 135元
  • 外观性质:无色液体。
  • F:19-21
  • MSDS 信息:乙基三氯硅烷(115-21-9).msds
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • MOL 文件:115-21-9.mol
  • TSCA:Yes

系列性分类


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