Allyltrichlorosilane 烯丙基三氯硅烷

CAS 107-37-9 MFCD00000486

化学结构图

107-37-9
SMILES: C=CC[Si](Cl)(Cl)Cl

化学属性

Mol. FormulaC3H5Cl3Si
Mol. Weight176
Refractive indexn20/D 1.443(lit.)
Boiling Point116
Density1.211
Flash Point18°(64°F)
TSCAYes
Vapor Density>;1 (vs air)
Vapor Pressure10 mmHg ( 16.1 °C)

别名和识别编码

Chemical NameAllyltrichlorosilane
CAS Number107-37-9
PubChem Substance ID7867
EC Number203-485-9
Beilstein Registry Number1743449
MDL NumberMFCD00000486
Synonym 三氯烯丙基硅烷 {uni_hamburg} trichloro-2-propenyl-silane 烯丙基三氯硅烷(稳定了的) Silane, trichloro-2-propenyl- allyltrichloro-silan Allyl trichlorosilane, stabilized Trichlor-2-propenylsilan Silane, trichloroallyl- Allyltrichlorsilan allyl-trichloro-silane trichloroallyl-silan allyltrichlorosilane trichloro-2-propenyl-silan Propen-3-yltrichlorosilane silane, trichloro-2-propenyl- allyltrichlorosilane,stabilized allylsilicone 丙烯基三氯硅烷 烯丙基三氯硅烷 ALLYLTRICHLOROSILANE 烯丙基三氯硅 Allyl trichloro silane Allyl trichlorosilane Allyl-trichlorsilan Silane, allyltrichloro- 3-TRICHLOROSILYLPROPENE Allylsilicone trichloride propen-3-yltrichlorosilane TRICHLOROALLYLSILANE allylsiliconetrichloride
Chemical Name Translation烯丙基三氯硅烷
Wiswesser Line NotationG-SI-GG2U1
LabNetwork Molecule IDLN01353106
InChIInChI=1S/C3H5Cl3Si/c1-2-3-7(4,5)6/h2H,1,3H2
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分类

  • Chemical Synthesis, Materials Science, Micro/NanoElectronics, Protecting and Derivatizing Reagents, Protection and Derivatization, Self Assembly & Contact Printing, Self-Assembly Materials, Silanes, Silicon-Based, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Micro/NanoElectronics, Protecting and Derivatizing Reagents, Protection and Derivatization, Self Assembly and Lithography, Self-Assembly Materials, Silanes, Silicon-Based, Synthetic Reagents, 材料科学
  • {SNA} Chemical Synthesis, Micro/NanoElectronics, Protecting and Derivatizing Reagents, Protection and Derivatization,
  • {SNA} Chemical Synthesis,

相关文献及参考

  • Aldrich MSDS 1 , 49:A / Corp MSDS 1 (1), 106:D / FT-IR 2 (3), 4361:C / FT-IR 1 (2), 1109:B / FT-NMR 1 (3), 652:B / IR-Spectra (2), 1318:F / IR-Spectra (3), 1541:H / RegBook 1 (2), 2965:C / Sax 6 , 173 / Structure Index 1 , 469:A:3 / Vapor Phase 3 , 1638:D
  • Beil. 4 ,IV,4260
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic momen

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 F,C
RTECSVV1530000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1724
Storage condition Moisture Sensitive Flammables area
Packing GroupII
Hazard Class8
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04219

其他信息

  • 储运特性:库房通风低温干燥; 与氧化剂、碱类、H发孔剂、氰化物分开存放
  • Acros Organics:烯丙基三氯硅烷 Allyltrichlorosilane, 95%(107-37-9)
  • 可燃性危险特性:遇氧化剂可燃; 遇水分解有毒氯化氢气体; 燃烧产生有毒氯化物烟雾
  • 毒性分级:高毒
  • 急性毒性:静注-小鼠 LD50: 56 毫克/公斤
  • 类别:腐蚀物品
  • 蒸气密度:>;1 (vs air)
  • TSCA:Yes
  • Sigma Aldrich:107-37-9(sigmaaldrich)
  • 灭火剂:砂土、雾状水、二氧化碳
  • 图谱信息:丙烯基三氯硅烷(107-37-9)红外图谱(IR1)
  • MOL 文件:107-37-9.mol
  • 外观性质:无色液体,带有辛辣刺激臭味。
  • 用途一:用于合成有机硅中间体及高分子聚合物
  • F:10-21
  • 用途二:用作硅酮的中间体
  • 蒸气压:10 mm Hg ( 16.1 °C)
  • 丙烯基三氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 313220250 丙烯基三氯硅烷 Allyltrichlorosilane 95% 25 GR 1762元 2010/06/21 313220050 丙烯基三氯硅烷 Allyltrichlorosilane 95% 5 GR 448元 2010/05/25 L03703 烯丙基三氯硅烷, 95% Allyltrichlorosilane, 95% 5g 389元
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:烯丙基三氯硅烷,95% Allyltrichlorosilane, 95%(107-37-9)
  • MSDS 信息:烯丙基三氯硅烷(稳定了的)(107-37-9).msds

系列性分类


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