2-Chloroethyl Chloroformate 2-氯乙基氯甲酸酯

CAS 627-11-2 MFCD00000646

化学结构图

627-11-2
SMILES: O=C(Cl)OCCCl

化学属性

Mol. FormulaC3H4Cl2O2
Mol. Weight143
Density1.385
Refractive index1.4460 to 1.4480
Boiling Point155-156
Vapor Pressure0.23 psi ( 20 °C)
Flash Point60°C(lit.)
Appearance 1.4460,相对密度1.385,能溶于苯、甲苯、酮、醚等有机溶剂。 氯甲酸-2-氯乙酯为无色至浅黄色透明液体,具有强烈刺激性和催泪性,b.p.155~156℃,n D 20

别名和识别编码

Chemical Name2-Chloroethyl Chloroformate
Synonym 1-chloro-2-chlorocarbonyloxy-ethane 1-chloroethyl carbonochloridate 2-CHLOROETHYL CHLOROFORMATE 2-Chloroethoxycarbonyl chloride 2-Chloroethyl chlorocarbonate 2-chloroethoxycarbonylchloride Chlorameisensäure-2-chlorethylester Chloroformic acid beta-chloroethyl ester TL 207 chlorocarbonic acid 2-chloro-ethyl ester chloroformicacid,beta-chloroethylester tl207 氯甲酸-2-氯乙基酯 氯甲酸-2-氯乙酯
CAS Number627-11-2
EC Number210-982-4
Beilstein Registry Number506639
MDL NumberMFCD00000646
PubChem Substance ID87566085
Reaxys-RN506639
Chemical Name Translation2-氯乙基氯甲酸酯
Wiswesser Line NotationGVO2G
LabNetwork Molecule IDLN00200571
InChIInChI=1S/C3H4Cl2O2/c4-1-2-7-3(5)6/h1-2H2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 酰胺类杀菌剂
  • {uni_hamburg} no charge; carbonyl chloride; 1fragment
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R23 Toxic by inhalation 吸入有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLQ5950000
Hazard Codes 6.1 T
UN Number 2742 3277
Storage condition 0-10 0-10°C Refrigerator 储存温度2-8°C
Packing GroupII
Hazard Class6.1/3, 8
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,JUN1942

其他信息

  • 储运特性:库房低温通风干燥; 与食品原料分开存放
  • 类别:有毒物质
  • 毒性分级:高毒
  • TCI Shanghai:氯甲酸-2-氯乙基酯 2-Chloroethyl Chloroformate,>;98.0%(T)(627-11-2)
  • 可燃性危险特性:可燃; 火场分解有毒氯化物气体
  • 用途二:氯甲酸-2-氯乙酯是杀菌剂恶霜灵的中间体。
  • Sigma Aldrich:627-11-2(sigmaaldrich)
  • MSDS 信息:2-Chloroethyl chloroformate(627-11-2).msds
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 急性毒性:吸入-小鼠 LCL0: 200 毫克/立方米/10分
  • 氯甲酸氯乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1052 氯甲酸2-氯乙酯 2-Chloroethyl Chloroformate 500G 3540元 2014/06/02 C1052 氯甲酸2-氯乙酯 2-Chloroethyl Chloroformate 25G 457元
  • MOL 文件:627-11-2.mol
  • 用途三:有机合成。
  • 图谱信息:氯甲酸氯乙酯(627-11-2)Raman光谱 氯甲酸氯乙酯(627-11-2)核磁图( 13 CNMR) 氯甲酸氯乙酯(627-11-2)核磁图( 1 HNMR) 氯甲酸氯乙酯(627-11-2)红外图谱(IR1) 氯甲酸氯乙酯(627-11-2)质谱(MS)
  • 方法一:其制备方法是在通光气釜内加入氯乙醇,启动搅拌,然后通过光气流量计通入光气。通光气温度为40~50℃,继续通光气20~24h,接近终点时取样分析,达标后停止通光气,然后通氮气赶走光气和氯化氢,光气进行破坏分解,赶气至pH=5~6,取样分析为产品。 ClCH 2 CH 2 OH+COCl 2 →ClCOOCH 2 CH 2 Cl+HCl↑+CO 2 ↑
  • 上游原料:盐酸 --> 2-氯乙醇 --> 流量计
  • 用途一:用作医药、农药用中间体

系列性分类


相关产品推荐