Malonyl Chloride 丙二酰氯

CAS 1663-67-8 MFCD00000735

化学结构图

1663-67-8
SMILES: O=C(Cl)CC(=O)Cl

化学属性

Mol. FormulaC3
Mol. Weight141
Density1.449 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.465(lit.)
Boiling Point60°C/28mmHg(lit.)
Flash Point47°C(lit.)
Solubility溶于乙醚、乙酸乙酯。
TSCAYes
Stability对湿度敏感

别名和识别编码

Chemical NameMalonyl Chloride
Synonym PROPANEDIOYL CHLORIDE 丙二酰氯 Propanedioyl dichloride Malonyl dichloride, GC 97% Malonic acid chloride Propanedioic acid dichloride 二氯化丙二酰 Malonyl dichloride MALONYL DICHLORIDE 98+% MALONYL CHLORIDE pract Malonyldichlorid MALONYL CHLORIDE Prodipionyl Malonsäuredichlorid malonyl chloride 丙二酰二氯
CAS Number1663-67-8
EC Number216-772-9
Beilstein Registry Number2(1)252
MDL NumberMFCD00000735
PubChem Substance ID87572871
Reaxys-RN774044
Chemical Name Translation丙二酰氯
InChIKeySXYFKXOFMCIXQW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224045
InChIInChI=1S/C3H2Cl2O2/c4-2(6)1-3(5)7/h1H2
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分类

  • {uni_hamburg} no charge; carbonyl chloride; 1fragment
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

产品应用

  • 有机合成。

相关文献及参考

  • Beilstein:2(1)252
  • Short: II/25C
  • Short: III/20a

安全信息

Signal word
GHS Symbol
WGK Germany1
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
  • R10 Flammable 易燃
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P304+P340+P310
  • P403+P235
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P241+P242+P243
  • P303+P361+P353+P310+P363
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
UN Number 2920
Packing GroupII
Storage condition 0-10 0-10°C 储存温度2-8°C 2-8°C
Hazard Class8/3
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 图谱信息:丙二酰氯(1663-67-8)核磁图( 13 CNMR) 丙二酰氯(1663-67-8)质谱(MS) 丙二酰氯(1663-67-8)红外图谱(IR1)
  • 外观性质:黄色液体。
  • 丙二酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0882 丙二酰氯 Malonyl Chloride 25G 1200元 2014/06/02 M0882 丙二酰氯 Malonyl Chloride 10G 698元 2010/06/21 125280250 丙二酰氯 Malonyl dichloride 97% 25 GR 1299元
  • 遇水和乙醇分解。溶于乙醚和乙酸乙酯。有催泪性的腐蚀性。
  • Sigma Aldrich:1663-67-8(sigmaaldrich)
  • MSDS 信息:丙二酰氯(1663-67-8).msds
  • 下游产品:丙二酸二(乙硫醇)酯
  • Acros Organics:丙二酰二氯 Malonyl dichloride, 97%(1663-67-8)
  • F:8-10
  • 海关编码:29171990
  • 用途一:可作为优良的酰化剂，用于有机合成
  • MOL 文件:1663-67-8.mol
  • TCI Shanghai:丙二酰氯 Malonyl Chloride,>;97.0%(T)(1663-67-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Acyl halide
  2. acyl chloride

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