1,2-Dichlorotetrafluoroethane 1,2-二氯四氟乙烷

CAS 76-14-2 MFCD00000778

化学结构图

76-14-2
SMILES: FC(F)(Cl)C(F)(F)Cl

化学属性

Mol. FormulaClCF2CF2Cl
Mol. Weight170.92
Vapor Density5.93 (vs air)
Boiling Point3.8 °C(lit.)
Vapor Pressure1427 mmHg ( 20 °C)
Melting Point-94 °C(lit.)
Solubility不溶于水,溶于多数有机溶剂。
Density1,44 g/cm3

别名和识别编码

Chemical Name1,2-Dichlorotetrafluoroethane
Synonym {uni_hamburg} F 114 Genetron 114 arcton114 HALOCARBON 1,1,2,2-四氟-1,2-二氯乙烷 arcton33 Fluorane Dichlorotetrafluoroethane Arcton 114 1,2-Dichloro-1,1,2,2-tetrafluoroethane Arcton 33 caswellno326 克立氟烷 二氯四氟乙烷 cr 1,1,2, 1,2-dichlorotetrafluoro-ethan R 114 (halocarbon) FLON-114 Genetron 316 Fluorocarb 1,2-dichloro-1,1,2,2-tetrafluoro-ethane 1,2-dichloro-1,1,2,2-tetrafluoroethane 1,2-dichlorotetrafluoroethane 1,2-DICHLOROTETRAFLUOROETHANE Cryofluoran 1,2-dichloro-tetrafluoro-ethane 氟利昂114 Propellant 114 {uni Halocarbon 114 1,2-Dichloroperfluoroethane ethane, 1,2-dichloro-1,1,2,2-tetrafluoro- Frigiderm Ucon 114 Ethane, 1,2-dichlorotetra 1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE 1,1,2,2-Tetrafluoro-1,2-Dichloroethane 1,1,2,2-Tetrafluor-1,2-dichlorethan {Che C2Cl2F4 (1,2-dichloro-1,1,2,2-tetrafluoro-ethane) 1,2-二氯四氟乙烷 freon 114 1,1,2,2-Tetrafluoro-1,2-dichloroethane Ledon 114 Cryofluoran (R 114) 1,2-dichloro-1,1,2,2-tetrafluoro-ethan 1'2-Dichlor-1'1'2& Fron 114 Cryofluorane F 114 (halocarbon) criofluorano Refrigerant Frigen 114 1,2-Dichlor-1,1,2,2-tetrafluorethan R-114 Tetrafiuorodichlo DICHLOROTETRAFLUOROETHANE
PubChem Substance ID6429
EC Number200-937-7
MDL NumberMFCD00000778
CAS Number76-14-2
Chemical Name Translation1,2-二氯四氟乙烷
Merck Number13,2633
Wiswesser Line NotationGXFFXGFF
Beilstein Registry Number1740333
InChIInChI=1S/C2Cl2F4/c3-1(5,6)2(4,7)8
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Specialty Gases, Synthetic Reagents

相关文献及参考

  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oil

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere 通过破坏上层大气臭氧层而危害公众健康和环境。
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
Personal Protective Equipment Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECSKI1101000
Precautionary statements
  • P410+P403
  • P502 Refer to manufacturer/supplier for information on recovery/recycling 回收/循环再生产的信息,请参阅制造商/供应商
Signal word Warning
Safety Statements
  • S59 Refer to manufacturer/supplier for information on recovery/recycling 参考生产厂家/供货商提供的回收/再生利用信息;
Hazard Codes N
Risk Statements
  • R59 Dangerous for the ozone layer 对臭氧层有危害
Hazard Class2.2
UN Number UN 1958 2.2
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 75 pph/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 72 pph/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,1976

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0520424

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 70 pph/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,1976

其他信息

  • 用途一:用作发泡剂、制冷剂和气雾剂等
  • 爆炸物危险特性:高热钢并可爆
  • Sigma Aldrich:76-14-2(sigmaaldrich)
  • 蒸气密度:5.93 (vs air)
  • MSDS 信息:二氯四氟乙烷(76-14-2).msds
  • 毒性分级:低毒
  • 类别:不燃; 无毒气体
  • 蒸气压:1427 mm Hg ( 20 °C)
  • 用途二:用作致冷剂,喷雾用喷射剂,泡沫聚合体起泡剂以及介电气体等。
  • 上游原料:氢氟酸 --> 六氯乙烷 --> 1,1,2-三氟三氯乙烷 --> 五氧化二锑 --> 三氯三氟乙烷
  • 急性毒性:吸入- 大鼠 LCL0: 720000 PPM/ 30分;吸入- 小鼠 LCL0: 700000 PPM/ 30分;
  • 外观性质:无色气体,有类似氯仿气味。
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与易燃物分开存放
  • 职业标准:TWA 7000 毫克/ 立方米; STEL 8750 毫克/立方米
  • 方法一:六氯乙烷与氟化氢在催化剂五氧化锑存在下进行反应,反应产物经碱洗、水洗、分馏、提纯,得到主产品1,1,2-三氟-1,2,2-三氯乙烷(氟里昂-113),同时副产该品。
  • 可燃性危险特性:常温不燃; 高热产生有毒氟化物气体; 臭氧消耗物质
  • MOL 文件:76-14-2.mol
  • 灭火剂:本身就是灭火剂

系列性分类


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