Trichlorofluoromethane 一氟三氯甲烷

CAS 75-69-4 MFCD00000784

化学结构图

75-69-4
SMILES: FC(Cl)(Cl)Cl

化学属性

Mol. FormulaCCl3F
Mol. Weight137.36
Refractive index1.3821
Boiling Point23.7°C
Density1.494
Melting Point-111--110°C
Vapor Density5.04 (vs air)
Vapor Pressure12.85 psi ( 20 °C)
Solubility不溶. 0.124 G/100 ML
Flash Point2 °C

别名和识别编码

Chemical NameTrichlorofluoromethane
Synonym {uni_hamburg} Propellant 11 Fluortrichlormethan NCI-C04637 { Monofluor-trichlormethan Electro-CF 11 Algofrene type 1 r11, Refrigerant Trichloromonofluoromethane freon HE FLON-11 Fl refrigerant R11 arcton11 Electro CF 11 Fluorotrojchlorometan R 11SS Arcton 9 t {Ch Refrigerant R 11 Ledon 11 {uni_hambur {Chemicalbo Ucon flurocarbon 11 Algofrene Type 1 Trichlorofluorocarbon F 11 Fluon 11 trichloro-fluoro-methane Frigen 11 FC 11 (halocarbon) HALOCARBON 11 {ALD FKW 11 CFC 11 Frigen S 11 Frigen 11A Fluorotrichloromet {uni Monofluorotrichloromethane Freon 11B flurotrichloromethane 三氯氟甲烷溶液 {Chem {uni_ha Isceon 131 Daiflon S 1 trichlorofluoromethane {un Flurotrichloromethane; Fluorocarbon 11 Eskimon Fluorocarbon 11 Asahifron11 Arcton 11 CFCl3 CFC-11 tric Halocarbon 11 caswe TRICHLOROFLUOROMETHANE 三氯氟甲烷,氟利昂-11 "Forane 11" Trichlorfluormethan 氟利昂-11 Isotron 11 Genetron 11SBA Freon MF Fluor freon 11 Trichloromethyl fluoride 氟三氯甲烷 freon-11 Kaltron 11 {Che 制冷剂-11 Freon 11A Genet
CAS Number75-69-4
PubChem Substance ID6389
EC Number200-892-3
Beilstein Registry Number1732469
MDL NumberMFCD00000784
Chemical Name Translation一氟三氯甲烷
Merck Number13,9714
Wiswesser Line NotationGXGGF
LabNetwork Molecule IDLN01747533
InChIInChI=1S/CCl3F/c2-1(3,4)5
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分类

  • Allergens, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Application, CFCs, Chemical Class, Chloro, Chromatography, Cosmetic Standards, Cosmetics, Environmental Standards, Fluoro, Halogenated, T, T-Z, TP - TZ, Volatiles/ Semivolatiles
  • {uni_hamburg} no charge; 1fragment
  • {SA} Alkyl, Alkyl Fluorinated Building Blocks, Building Blocks, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Buil

产品应用

  • 主要用作中温致冷剂，抽提剂，灭火剂和聚氨基甲酸酯泡沫塑料的发泡剂。该品毒性比氯烃低。

相关文献及参考

  • Merck: 14,9640
  • Short: II/19c
  • Merck: 14,9640 Beilstein: 1,IV,54
  • Short: II/19a

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,T,N Xn;N,Xi,N,Xn,T,F F,Xi,N Xn;N
Hazard statements
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere 通过破坏上层大气臭氧层而危害公众健康和环境。
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSPB6125000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S59 Refer to manufacturer/supplier for information on recovery/recycling 参考生产厂家/供货商提供的回收/再生利用信息；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S24 Avoid contact with skin 避免皮肤接触；
Risk Statements
  • R59 Dangerous for the ozone layer 对臭氧层有危害
  • R20 Harmful by inhalation 吸入有害
  • R11 Highly flammable 非常易燃
  • R36 Irritating to eyes 刺激眼睛
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R23 Toxic by inhalation 吸入有毒
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
UN Number 3082 2517
Storage condition 2-8°C 储存温度2-8°C
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >352 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0520424

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 pph/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,1976

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 50000 ppm/30M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Lungs, Thorax, or Respiration - fibrosing alveolitis
   Liver - other changes
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,19

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 25 pph/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJTXAZ European Journal of Toxicology and Environmental Hygiene.  (Paris,
   France)  V.7-9, 1974-76. For publisher information, see TOERD9.
   Volume(issue)/page/year: 9,385,1976

Restrict 危险品

其他信息

  • 上游原料:盐酸 --> 四氯化碳 --> 氢氟酸 --> 五氯化锑 --> 二氯二氟甲烷
  • 职业标准:TWA 5600 毫克/ 立方米; STEL 7000 毫克/立方米
  • 毒性分级:中毒
  • 防护措施:毒性比氯代烃的小，但有报道，浓度在10%以上时，能引起兴奋、痉挛，最后陷入麻醉状态。人体吸入最低中毒浓度（半数）5%（30min)。小鼠腹腔注射LD50为1743mg/kg。
  • 外观性质:无色液体或气体，有醚味。
  • 类别:有害气体
  • Sigma Aldrich:75-69-4(sigmaaldrich)
  • 方法一:主要采用四氯化碳与氟化氢液相接触法，甲烷氟氯化法生产。液相接触法以五氯化锑为催化剂，四氯化碳和无水氟化氢反应生成一氟三氯甲烷和二氟二氯甲烷，副产盐酸。反应产物除去氯化氢，经洗涤，脱水，脱气，分馏而得成品。图76是四氯化碳制备一氟三氯甲烷的一种流程。 甲烷氟氯化法由甲烷，氯气和氟化氢在370-470℃，0.39-0.59MPa压力下，接触反应4-10秒，得到一氟三氯甲烷和二氟二氯甲烷。一氟三氯甲烷和二氟二氯甲烷混合物（两个组分各占50%），以甲烷计收率在99%以上，分离后的产品纯度都在99。95%以上。甲烷 132氯气 2380氟化氢 260盐酸 1480
  • 下游产品:二乙胺基三氟化硫
  • MSDS 信息:三氯氟甲烷(75-69-4).msds
  • 用途一:用作制冷剂、发泡剂，也用于生产海绵、医药和农药等
  • 用途二:主要用作中温致冷剂，抽提剂，灭火剂和聚氨基甲酸酯泡沫塑料的发泡剂。该品毒性比氯烃低。
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与易燃物分开存放
  • Hazard Note:Irritant
  • 常规方法:用钢瓶盛装，受压29.4MPa。火车、汽车运输。按一般化学品规定贮运。
  • 爆炸物危险特性:高热可爆
  • 可燃性危险特性:常温不燃; 高热产生有毒氟化物， 氯化物气体
  • 灭火剂:视周围化学品而定
  • MOL 文件:75-69-4.mol
  • 常温下为无色透明液体，不燃不爆，毒性低，具有良好的热稳定性和化学稳定性，密度高，粘性低，几乎不溶于水，但能溶于醇、醚、油和很多碳氢化合物。它是一种高温致冷剂，能使环境温度控制在0℃～10℃之间。
  • 急性毒性:吸入- 大鼠 LC50: 13000 PPM/ 15分; 吸入- 小鼠 LC50: 10000 PPM/ 30分

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Stable Isotopes 稳定同位素
  3. Alphabetical Listings for Stable Isotope Labeled Products
  4. T - Alphabetical Listings
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Alkyl Fluorinated Building Blocks - Other Fluorinated Organic Building Blocks
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Application - Analytical Standards
  4. Cosmetics - Application
  5. Allergens - Cosmetics
  6. CFCs - Allergens
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TP - TZ - T
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Gas Cylinders

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