Chlorotrifluoroethylene 三氟氯乙烯

CAS 79-38-9 MFCD00000822

化学结构图

79-38-9
SMILES: FC(F)=C(F)Cl

化学属性

Mol. FormulaClCF=CF2
Mol. Weight116.47
Vapor Density4.13 (vs air)
Boiling Point-28.4 °C(lit.)
Melting Point-158 °C(lit.)
Flash Point-28°C
Solubility溶于醚。
Density1,305 g/cm3

别名和识别编码

Chemical NameChlorotrifluoroethylene
Synonym trifluorochloroethene cfe F 1113 1,1,2-Trifluoro-2-chloroethylene Monochlorotrifluoroethylene chloro-trifluoro-ethene Trifluorovinyl chloride Chlorotrifluoroethylene Trifluoromonochloroethylene CHLOROTRIFLUOROETHENE 氯三氟乙烯 1-Chlor-1,2,2-trifluorethen Trifluorchlorethylen Chlortrifluoraethylen chlorotrifluoro-ethylen chlorotrifluoro-ethen CHLOROTRIFLUOROETHYLENE Chlortrifluorethen FC-1113 1-Chloro-1,2,2-trifluoroethylene TRIFLUORO CHLORO ETHYLENE trifluorochloroethylene Daiflon R 1113 Genetron 1113 ethene, chlorotrifluoro- 2-Chloro-1,1,2-trifluoroethylene ethylene, chlorotrifluoro- Fluoroplast 3 CFC 1113 1-chloro-1,2,2-trifluoroethene Ethylene, chlorotrifluoro- CTFE Ethylene, trifluorochloro- Trifluorochloroethylene fluoroplast3 C2F3Cl Ethene, chlorotrifluoro- chlorotrifluoroethene Chlortrifluorethylen Trithene 三氟氯乙烯 chlorotrifluoroethylene Kältemittel R 1113 2-Chloro-1,1,2-trifluoroethene Trifluorochloromethylene Ethene,chlorotrifluoro- 1-Chloro-1,2,2-trifluoroethene
MDL NumberMFCD00000822
CAS Number79-38-9
PubChem Substance ID6594
EC Number201-201-8
Chemical Name Translation三氟氯乙烯
Wiswesser Line NotationGYFUYFF
Beilstein Registry Number1740373
LabNetwork Molecule IDLN02204529
InChIInChI=1S/C2ClF3/c3-1(4)2(5)6
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Specialty Gases, Synthetic Reagents

相关文献及参考

  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19c Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54893-9 ISBN: 978-3-540-54893-5 Internet Resource: DOI:10.1007/b44435 RefComment: 8 figs., XI, 295 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplem

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H220 Extremely flammable gas 极易燃气体。
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
  • H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
Personal Protective Equipment Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECSKV0525000
Precautionary statements
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P410+P403
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
Hazard Codes F+,Xn F+,Xn,T,F F+;Xn
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
Risk Statements
  • R12 Extremely flammable 极端易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
UN Number 1082 UN 1082 2.3
Hazard Class2.3
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 175 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ABMGAJ Acta Biologica et Medica Germanica.  (Berlin, Ger. Dem. Rep.) V.1-41,
   1958-82.  For publisher information, see BBIADT. Volume(issue)/page/year:
   21,377,1968

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1000 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Gastrointestinal - other changes
REFERENCE :
   FLCRAP Fluorine Chemistry Reviews.  (Marcel Dekker, 270 Madison Ave., New
   York, NY 10016) V.1-    1967-  Volume(issue)/page/year: 1,197,1967

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 4300 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 21(5),36,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 268 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ABMGAJ Acta Biologica et Medica Germanica.  (Berlin, Ger. Dem. Rep.) V.1-41,
   1958-82.  For publisher information, see BBIADT. Volume(issue

其他信息

  • 蒸气密度:4.13 (vs air)
  • 方法一:1934年德国最早制得三氟氯乙烯，1949年美国实现了工业化生产。工业上普遍采用的方法是由三氟三氯乙烷脱氯而得。一般以锌粉为脱氯剂，以甲醇为溶剂，反应温度为50-150℃，反应压力为2.08MPa，反应时间为3-4s。将含有锌粉的甲醇悬浮液与三氟三氯乙烷一同送进反应器，生成的氯化锌从反应物中分离出来，反应产物送往初馏塔和精馏塔后，得纯三氟氯乙烯。原料消耗定额：三氟三氯乙烷1830kg/t、甲醇（>95%）1080kg/t、锌粉（>95%）840kg/t。
  • 毒性分级:高毒
  • Sigma Aldrich:79-38-9(sigmaaldrich)
  • 爆炸物危险特性:受热、日晒钢瓶可爆; 泄漏放出剧毒可燃气体
  • 类别:有害气体
  • 用途二:三氟氯乙烯聚合成聚三氟氯乙烯，具有优良的电性能，耐热和耐化学性能次于聚四氟乙烯，但加工容易，可制成塑料、薄膜、涂料等制品，工作温度为-196～199℃。也是氟塑料、氟橡胶、致冷剂、氟氯润滑油、氟烷麻醉剂的原料。用于以氟取代甾体、碳水化合物中的羟基用作防腐剂。
  • 储运特性:库房通风低温干燥; 轻装轻卸
  • 用途一:用于制备聚三氟氯乙烯树脂及氟橡胶
  • MOL 文件:79-38-9.mol
  • 下游产品:聚三氟氯乙烯
  • 职业标准:STEL 5 毫克/ 立方米
  • 可燃性危险特性:明火易燃; 遇水或受热分解有毒氟化物和氯化物气体
  • 灭火剂:砂土、雾状水
  • Hazard Note:Flammable/Toxic
  • 外观性质:无色，微有乙醚气味的气体。
  • 上游原料:锌粉 --> 氯化锌 --> 硫代硫酸钠 --> 1,1,2-三氟三氯乙烷
  • MSDS 信息:三氟氯乙烯(79-38-9).msds
  • 急性毒性:吸入- 大鼠 LC50: 1000 PPM/ 4 小时; 口服- 小鼠 LD50: 268 毫克/ 公斤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Specialty Gases 特种气体
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Specialty Gases 特种气体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物

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