Chloromethyldichloromethylsilane (氯甲基)甲基二氯硅烷

CAS 1558-33-4 MFCD00000874

化学结构图

1558-33-4
SMILES: C[Si](Cl)(Cl)CCl

化学属性

Mol. FormulaC2H5Cl3Si
Mol. Weight163.50
Vapor Density>;1 (vs air)
Density1.284 g/mL at 25 °C(lit.)
Refractive index1.4480 to 1.4510
Boiling Point122°C(lit.)
Flash Point35°C(lit.)
TSCAYes
Solubility起反应
Appearance 微黄或无色透明液体，密度 1.284，沸点 121-122℃，折射率 1.448-1.451，闪点 35℃
Melting Point<0°C

别名和识别编码

Chemical NameChloromethyldichloromethylsilane
Synonym CC3275 inh-6573intermediate Dichlor(chlormethyl)methylsilan Methyldichloro(chloromethyl)silane CHLOROMETHYLDICHLOROMETHYLSILANE (CHLOROMETHYL)METHYLDICHLOROSILANE Dichlor(chlormethyl)(methyl)silan silane,dichloro(chloromethyl)methyl- (chloromethyl)dichloromethyl-silan dichloro(chloromethyl)methyl-silan {uni_hambur (氯甲基)二氯甲基硅烷 (Dichloromethylsilyl)chloromethane Chlormethyl-dichlor-methylsilan ChloromethylmethyldichlorosilaneCMMCS (Chloromethyl)dichloromethylsil Dichloro(chloromethyl)methylsilane CMMCS (氯甲基)甲基-二氯硅烷 methyl(chloromethyl)dichlorosilane Chloromethyldichloromethylsilane methyldichloro(chloromethyl)silane CH3SiCl2(CH2Cl) (CHLOROMETHYL)METHYLDICHLOROSILANE 97% (CHLOROMETHYL)METHYLDICHLOROSILANE, WACKER QUALITY dichloromethyl(chloromethyl)silane methyl (chloromethyl)dichlorosilane Chloromethyldichlorome Dichloro(chloromethyl)methylsi chloromethyl(methyl)dichlorosilane (氯甲基)二氯甲基硅烷, (氯甲基)甲基二氯硅烷 (Chloromethyl)methyldichlorosilane silane, dichloro(chloromethyl)methyl- (氯甲基)甲基二氯硅烷 (氯甲基)二氯甲基硅烷 (氯甲基)甲基二氯硅烷 DICHLORO(CHLOROMETHYL)METHYLSILANE (Chloromethyl)dichloromethylsilane (Chloromethyl)dichloromethylsilane, (Chloromethyl)methyldichlorosilane, Silane CMM1 甲基氯甲基二氯硅烷 SILANE CMM1 chloromethyl(methyl)dichloro-silane
MDL NumberMFCD00000874
CAS Number1558-33-4
Beilstein Registry Number4(4)4135
EC Number216-319-5
PubChem Substance ID87566370
Reaxys-RN969205
Chemical Name Translation(氯甲基)甲基二氯硅烷
LabNetwork Molecule IDLN00227146
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分类

  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Ke

安全信息

RTECSVV2160000
WGK Germany3
GHS Symbol
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+P233
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
Signal word Danger
Packing GroupII
UN Number 3362 2986 UN2920 UN 2927 6.1/PG 2
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R20 Harmful by inhalation 吸入有害
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S8 Keep container dry 保持容器干燥；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Storage condition Moisture Sensitive 0-10 0-10°C 储存温度：2-8°C
Hazard Codes C
Hazard Class6.1/3, 8

其他信息

  • Sigma Aldrich:1558-33-4(sigmaaldrich)
  • (氯甲基)甲基二氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1358 氯甲基(二氯)甲基硅烷 Chloromethyl(dichloro)methylsilane 25G 720元
  • 用途一:用于农药及硅系列中间体的合成
  • 蒸气密度:>;1 (vs air)
  • MOL 文件:1558-33-4.mol
  • TCI Shanghai:(氯甲基)甲基二氯硅烷 Chloromethyl(dichloro)methylsilane,>;97.0%(GC)(1558-33-4)
  • Alfa Aesar:(Chloromethyl)methyldichlorosilane, 97%(1558-33-4)
  • 图谱信息:(氯甲基)甲基二氯硅烷(1558-33-4)红外图谱(IR1)
  • 存储注意事项:氮气保护
  • F:10
  • MSDS 信息:Chloromethyldichloromethylsilane(1558-33-4).msds
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物

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