Bromochloromethane 氯溴甲烷

CAS 74-97-5 MFCD00000880

化学结构图

74-97-5
SMILES: ClCBr

化学属性

Mol. FormulaCH2BrCl
Mol. Weight129
Refractive index1.482
Vapor Density4.5 (vs air)
Boiling Point68°C
Vapor Pressure117 mmHg ( 20 °C)
Density1.991
Melting Point-88°C
Flash PointNone
TSCAYes
Solubility9 G/L (20 ºC)
Stability对光敏感

别名和识别编码

Chemical NameBromochloromethane
CAS Number74-97-5
Synonym Methane, bromochloro- ai3-15514 CH2BrCl (bromo-chloro-methane) CH2ClBr CBM Chlorobromomethane 溴氯甲烷;氯溴甲烷 Bromochloromethane? CB methane,bromochloro BCM CHLOROBROMOMETHANE Chlorbrommethan 溴氯甲烷 chlorobrom Bromchlormethan BROMOCHLOROMETHANE chloromethylbromide halon1011 bromochloromethane Mil-B-4394-B METHYLENE BROMOCHLORIDE halon-1011 氯溴次甲基 methane,bromochloro- bromochloro-methan bromo-chloro-methane 氯溴甲烷 亚甲基溴氯 Monochloromonobromomethane METHYLENE CHLOROBROMIDE Halon 1011 甲撑溴氯 Fluorocarbon 1011 Fluorocarbon1011 Mono-chloro-mono-bromo-methane Methylene bromochloride Methylene chlorobromide MIL-B-4394-B
MDL NumberMFCD00000880
PubChem Substance ID6333
EC Number200-826-3
Beilstein Registry Number1730801
Chemical Name Translation氯溴甲烷
Wiswesser Line NotationG1E
LabNetwork Molecule IDLN00221593
InChIInChI=1S/CH2BrCl/c2-1-3/h1H2
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分类

  • 600 Series Wastewater Methods, A-B, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Bromo, Chemical Class, Chloro, Chromatography, EPA, Environmental Standards, Halogenated, Method 601, Method Specific, Volatiles/ Semivolatiles
  • {uni_hamburg} no charge; 1fragment
  • {SNA} A-B, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Bromo,

产品应用

  • 溴氯甲烷作为医药、农药、杀菌剂、水处理剂等的中间体。

相关文献及参考

  • Beilstein: 1,IV,74
  • Short: II/19c
  • Short: II/19b

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H420 Harmspublichealthandtheenvironmentbydestroyingozoneintheupperatmospere 通过破坏上层大气臭氧层而危害公众健康和环境。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn;N Xi,N,Xn,T,F T Xn,N
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSPA5250000
Packing GroupIII
UN Number UN 1887 6.1/PG 3 UN1887 1887
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R59 Dangerous for the ozone layer 对臭氧层有危害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R20 Harmful by inhalation 吸入有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Safety Statements
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S59 Refer to manufacturer/supplier for information on recovery/recycling 参考生产厂家/供货商提供的回收/再生利用信息;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Storage condition Light Sensitive 2-8°C 避光保存
Hazard Class6.1(b)
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,390,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4300 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 29,382,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A062-138

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 28800 ppm/15M
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - tremor
REFERENCE :
   MRLR** U.S. Army, Chemical Corps Medical Laboratories Research Reports.
   (Army Chemical Center, Edgewood Arsenal, MD)  Volume(issue)/page/year:
   #113,1952

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 13,205,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 5 umol/L
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 13,205,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 mg/plate
REFERENCE :
   DHEFDK HEW Publication (FDA. United States).  (Washington, DC)  ?-1979(?).
   For publisher information, see HPFSDS.  Volume(issue)/page/year:
   FDA-78-1046,1978

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 1 umol/L
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 13,205,1987

其他信息

  • 用途二:溴氯甲烷作为医药、农药、杀菌剂、水处理剂等的中间体。
  • 毒性分级:中毒
  • 灭火剂:水
  • 急性毒性:口服- 大鼠 LD50: 5000 毫克/ 公斤; 口服- 小鼠 LD50: 4300 毫克/ 公斤
  • Sigma Aldrich:74-97-5(sigmaaldrich)
  • 职业标准:TWA 1050 毫克/ 立方米; STEL 1315 毫克/ 立方米
  • 图谱信息:溴氯甲烷(74-97-5)Raman光谱 溴氯甲烷(74-97-5)红外图谱(IR2) 溴氯甲烷(74-97-5)质谱(MS) 溴氯甲烷(74-97-5)核磁图( 1 HNMR) 溴氯甲烷(74-97-5)核磁图( 13 CNMR) 溴氯甲烷(74-97-5)红外图谱(IR1)
  • 类别:有毒物品
  • 溴氯甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L0313902 一溴一氯甲烷 500g 252元 2010/06/21 159130050 溴氯甲烷 Bromochloromethane 98% 5 ML 213元 2010/06/21 159130010 溴氯甲烷 Bromochloromethane 98% 1 LT 935元
  • 蒸气压:117 mm Hg ( 20 °C)
  • 下游产品:二溴甲烷
  • 挥发性有机化合物(VOCs)单组分标准液
  • 可燃性危险特性:本身不燃; 遇热分解卤化物有毒蒸气
  • 用途一:用于制药
  • 具有特殊甜味,微溶于水,水中溶解度: 9 g/l in water (20°C) ,能与大多数常规有机溶剂混溶。不易燃、不易爆,冰点低。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 蒸气密度:4.5 (vs air)
  • MOL 文件:74-97-5.mol
  • Acros Organics:溴氯甲烷 Bromochloromethane, 98%(74-97-5)
  • Hazard Note:Irritant
  • MSDS 信息:氯溴甲烷(74-97-5).msds
  • Alfa Aesar:溴氯甲烷,98% Bromochloromethane, 98%(74-97-5)
  • 外观性质:无色透明液体,有类似氯仿的特殊气味。

系列性分类


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