Chloromethyl pivalate 特戊酸氯甲酯
CAS 18997-19-8 MFCD00000884
化学结构图
SMILES: CC(C)(C)C(=O)OCCl
化学属性
| Mol. Formula | C6H11ClO2 |
|---|---|
| Mol. Weight | 151 |
| Refractive index | 1.4160 to 1.4180 |
| Boiling Point | 146-148 |
| Density | 1.045 |
| Flash Point | 40°C(lit.) |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Chloromethyl pivalate |
|---|---|
| Synonym | Chloromethyl trimethylacetate Chloromethyl trimethylacetate, Pivaloyloxymethyl chloride POM-Cl 新戊酸氯甲酯 特戊酸氯甲酯 |
| CAS Number | 18997-19-8 |
| PubChem Substance ID | 87575124 |
| EC Number | 242-735-1 |
| Beilstein Registry Number | 1560838 |
| MDL Number | MFCD00000884 |
| Chemical Name Translation | 特戊酸氯甲酯 |
| Reaxys-RN | 1560838 |
| InChIKey | GGRHYQCXXYLUTL-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00115611 |
| InChI | InChI=1S/C6H11ClO2/c1-6(2,3)5(8)9-4-7/h4H2,1-3H3 |
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分类
- {SNA} Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
- Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
相关文献及参考
- Beil. 2 ,IV,914
- Aldrich MSDS 1 , 421:A / Corp MSDS 1 (1), 809:B / FT-IR 1 (1), 648:A / FT-IR 2 (1), 1055:D / FT-NMR 1 (1), 1006:C / IR-Spectra (3), 383:B / IR-Spectra (2), 339:D / NMR-Reference 2 (1), 546:B / RegBook 1 (1), 733:G / Sigma FT-IR 1 (2), 383:C / Structure Index 1 , 112:A:8 / Vapor Phase 3 , 696:B
- Reagent for the N-protection of amines, e.g. adenine in the presence of K2CO3 in DMF, as pivaloyloxymethyl (Pom) derivatives, which have been found useful in the synthesis of sensitive nucleosides. The Pom group is cleaved in mild base, e.g. methanolic ammonia: J. Am. Chem. Soc., 89, 5439 (1967).
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H302+H312+H332
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R10 Flammable 易燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
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