cis-1,2-Dichloroethylene 顺-1,2-二氯乙烯

CAS 156-59-2 MFCD00000925

化学结构图

156-59-2
SMILES: Cl/C=C\Cl

化学属性

Mol. FormulaC2H2Cl2
Mol. Weight96.94
Refractive indexn20/D 1.449(lit.)
Boiling Point60 °C at 760 mmHg
Density1.284 g/mL at 25 °C(lit.)
Melting Point-80 °C
Flash Point4°C(lit.)

别名和识别编码

Chemical Namecis-1,2-Dichloroethenee
Synonym (Z)-1,2-dichloroethene {LY} (Z)-1,2-dichloroethene {} {LY} (Z)-1,2-dichloroethene {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloroethene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,2-dichloro
MDL NumberMFCD00000925
CAS Number156-59-2
PubChem Substance ID643833
EC Number205-859-7
Beilstein Registry Number1071208
Reaxys-RN1071208
Merck Number92
Chemical Name Translation顺-1,2-二氯乙烯
Wiswesser Line NotationG1U1G -Z
LabNetwork Molecule IDLN01269766
InChIInChI=1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1-
Canonical SMILESC(=C/Cl)/Cl
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Class, Chloro, Chromatography, D, DIA - DIC, Environmental Standards, Halogenated, Volatiles/ Semivolatiles
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19c Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54893-9 ISBN: 978-3-540-54893-5 Internet Resource: DOI:10.1007/b44435 RefComment: 8 figs., XI, 295 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplem

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSKV9420000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P307+P311
  • P308+P313
  • P308+P316
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S29 Do not empty into drains 不要排入下水道;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Hazard Codes F,Xn,T F,Xn
Risk Statements
  • R52/53
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R20 Harmful by inhalation 吸入有害
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R11 Highly flammable 非常易燃
UN Number 1150 UN 1150 3/PG 2 1230
Packing GroupII
Storage condition -20°C {LY} -20°C 0-10 0-10°C 0-60°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class3
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 65 gm/m3/2H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   AHBAAM Archiv fuer Hygiene und Bakteriologie.  (Munich, Fed. Rep. Ger.)
   V.101-154, 1929-71.  For publisher information, see ZHPMAT.
   Volume(issue)/page/year: 116,131,1936

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 20 gm/m3/6H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Behavioral - convulsions or effect on seizure threshold
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   AHBAAM Archiv fuer Hygiene und Bakteriologie.  (Munich, Fed. Rep. Ger.)
   V.101-154, 1929-71.  For publisher information, see ZHPMAT.
   Volume(issue)/page/year: 116,131,1936

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 4300 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 5,1629,1984

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 40 mmol/L
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   4,365,1984

TYPE OF TEST            : Host-mediated assay
TEST SYSTEM             : Rodent - mouse Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 1300 mg/kg
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   4,365,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   4,365,1984

其他信息

  • F:1-8-10
  • 顺-1,2-二氯乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 S0625 顺-1,2-二氯乙烯(1mg/ml的甲醇溶液)[用于水分析] cis-1,2-Dichloroethylene (1mg/ml in Methanol) [for Water Analysis] 1ML 240元 2014/06/02 D0367 顺-1,2-二氯乙烯(含稳定剂MEHQ) cis-1,2-Dichloroethylene (stabilized with MEHQ) 25G 1070元 2010/06/21 113380025 顺-1,2-二氯乙烯 cis-1,2-Dichloroethylene 97%, stabilized 2.5 ML 754元
  • 爆炸物危险特性:与空气混合形成爆炸性混合物;
  • 毒性分级:中毒
  • 可燃性危险特性:易燃; 受热分解有毒的光气和氯化氢等气体
  • Sigma Aldrich:156-59-2(sigmaaldrich)
  • 灭火剂:泡沫, 干粉, 二氧化碳, 砂土
  • 类别:易燃液体
  • 图谱信息:顺-1,2-二氯乙烯(156-59-2)红外图谱(IR1) 顺-1,2-二氯乙烯(156-59-2)质谱(MS) 顺-1,2-二氯乙烯(156-59-2)核磁图( 1 HNMR) 顺-1,2-二氯乙烯(156-59-2)核磁图( 13 CNMR)
  • MOL 文件:156-59-2.mol
  • 职业标准:TLV-TWA 790 毫克/立方米; STEL 990 毫克/立方米
  • TCI Shanghai:顺-1,2-二氯乙烯(1mg/ml的甲醇溶液)[用于水分析] cis-1,2-Dichloroethylene (1mg/ml in Methanol) [for Water Analysis](156-59-2)
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运存放
  • 急性毒性:吸入-大鼠 LC50: 13700 ppm; 吸入-小鼠 LCL0: 65000 毫克/立方米/2小时
  • Acros Organics:顺式-1,2-二氯乙烯 cis-1,2-Dichloroethylene, stabilized, 97%(156-59-2)

系列性分类


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