Tris(2-chloroethyl) phosphate 磷酸三(2-氯乙基)酯

CAS 115-96-8 MFCD00000967

化学结构图

115-96-8
SMILES: O=P(OCCCl)(OCCCl)OCCCl

化学属性

Mol. FormulaC6H12Cl3O4P
Mol. Weight285.49
Refractive index1.4710 to 1.4750
Boiling Point192 °C at 10 mmHg
Density1.39
Flash Point222°C(lit.)
Melting Point-51 °C
Solubility7 G/L (20 ºC)
Vapor Pressure<;10 mmHg ( 25 °C)

别名和识别编码

Chemical NameTris(2-chloroethyl) Phosphate
CAS Number115-96-8
Synonym Tris(2-chloroethyl) phosphate {LY} Tris(2-chloroethyl) phosphate tri(chloroethyl)phosphate tris(2-chlorethyl)orthophosphate tris(2-chloroethyl)phosphate tris(chloroethyl)phosphate {} {LY} Tris(2-chloroethyl) phosphate {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-chloroethyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-chloroethy
PubChem Substance ID8295
EC Number204-118-5
MDL NumberMFCD00000967
Beilstein Registry Number1710938
Reaxys-RN1710938
Chemical Name Translation磷酸三(2-氯乙基)酯
LabNetwork Molecule IDLN00200312
InChIInChI=1S/C6H12Cl3O4P/c7-1-4-11-14(10,12-5-2-8)13-6-3-9/h1-6H2
Canonical SMILESO=P(OCCCl)(OCCCl)OCCCl
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {Chemicalbook} 化工助剂: 纺织染整助剂: 纺织品后整理剂
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

产品应用

  • A human urinary organophosphate flame retardant metabolite.

相关文献及参考

  • Tilson, H., et al.: Toxicol. Appl. Pharmacol., 106, 254 (1990),
  • Saboori, A., et al.: J. Biol .Chem., 265, 19792 (1990),
  • Beil. 1 ,II,337
  • Aldrich MSDS 1 , 1813:D / Corp MSDS 1 (2), 3527:D / FT-IR 1 (1), 926:C / FT-IR 2 (1), 1578:D / FT-NMR 1 (1), 1497:B / IR-Spectra (2), 493:D / IR-Spectra (3), 556:E / NMR-Reference 2 (2), 876:D / RegBook 1 (1), 1115:M / Sax 6 , 711 / Structure Index 1 , 173:A:1
  • Short: III/38A Title: Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38A Year: 1996 Keyword: organicmetallic compounds; inorganic compounds; refractive index; liquids; mixtures ISBN: 3-540-60539-8 ISBN: 978-3-540-60539-3 Internet Resource: DOI:10.1007/b55612 RefComment: VII, 400 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/18A Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organometallic and Organononmetallic Liquids, Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18A Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures ISBN: 3-540-64584-5 ISBN: 978-3-540-64584-9 Internet Resource: DOI:10.1007/b68239 RefComment: VII, 409 pages.
  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dy

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 T,N Xn,N Xn;N
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKK2450000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P307+P311
  • P308+P311
  • P308+P313
  • P308+P316
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R51/53
  • R60 May impair fertility 可能降低生殖能力
UN Number 2810 UN 2810 6.1/PG 3
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 外观性质:无色或淡黄色油状液体。
  • 毒性分级:中毒
  • MSDS 信息:磷酸三(-2-氯乙酯)(115-96-8).msds
  • 急性毒性:口服- 大鼠 LD50: 1230 毫克/ 公斤; 口服- 小鼠 LD50:1866 毫克/ 公斤
  • TCI Shanghai:磷酸三(β-氯乙基)酯 Tris(2-chloroethyl) Phosphate,>;97.0%(GC)(115-96-8)
  • 可燃性危险特性:可燃; 火场分解有毒氯化氢， 磷氧化物气体
  • 图谱信息:磷酸三(2-氯乙基)酯(115-96-8)核磁图( 13 CNMR) 磷酸三(2-氯乙基)酯(115-96-8)红外图谱(IR2) 磷酸三(2-氯乙基)酯(115-96-8)红外图谱(IR1) 磷酸三(2-氯乙基)酯(115-96-8)核磁图( 1 HNMR) 磷酸三(2-氯乙基)酯(115-96-8)质谱(MS)
  • 方法二:三氯氧磷和环氧乙烷以偏钒酸钠为催化剂，在50℃反应，反应物经中和、水洗、真空脱水脱低沸物，即得成品。也可用氯乙醇做原料，与三氯氧磷或三氯化磷反应来制造磷酸三（2-氯乙基）酯。
  • MOL 文件:115-96-8.mol
  • 用途三:阻燃剂，广泛用于醋酸纤维素、硝基纤维素、乙基纤维素、聚氯乙烯、聚氨酯、聚醋酸乙烯和酚醛树脂。用作阻燃性增塑剂。还可用作金属萃取剂、润滑油和汽油添加剂，以及聚酰亚胺加工改性剂。大鼠口毒性LD50为1410mg/kg。
  • 类别:有毒物质
  • 用途一:主要用于聚氨酯泡沫阻燃以及聚氯乙烯阻燃增塑等
  • 方法一:将326 kg三氯氧磷和1.0 kg偏钒酸钠投入反应釜中。充氮驱尽反应釜中的空气，在真空下通入650 kg环氧乙烷，于45～50 ℃下搅拌2～3 h。蒸出过量的环氧乙烷后加碱中和至中性，水洗，真空脱水。得成品。
  • 灭火剂:水, 二氧化碳, 泡沫, 砂土
  • 上游原料:三氯氧磷 --> 曙光红(四溴荧光素) --> 2-氯乙醇 --> 四氯化钛 --> 亚磷酸三苯酯 --> 环氧 --> 钒酸钠
  • 储运特性:库房低温, 通风, 干燥
  • 磷酸三(2-氯乙基)酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0268 磷酸三(2-氯乙基)酯 Tris(2-chloroethyl) Phosphate 25G 129元 2010/06/21 152810250 磷酸三(2-氯乙基)酯 Tris(2-chloroethyl) phosphate 97% 25 GR 208元 2010/06/21 152810010 磷酸三(2-氯乙基)酯 Tris(2-chloroethyl) phosphate 97% 1 KG 492元
  • 用途二:本品广泛用于化纤织物、醋酸纤维素作阻燃剂，除具有自熄性外，还可改善耐水性、耐寒性及抗静电性。一般用量5～10份。
  • 蒸气压:<;10 mm Hg ( 25 °C)
  • Sigma Aldrich:115-96-8(sigmaaldrich)
  • Acros Organics:三（2-氯乙基）磷酸酯 Tris(2-chloroethyl) phosphate, 97%(115-96-8)
  • 刺激数据:皮肤- 兔 10 毫克/ 24小时 轻度; 眼睛- 兔 500 毫克/ 24小时 轻度

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds
  1. Materials Science 材料科学
  2. Plasticizer

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