Vinyl(2-Chloroethyl)Ether 乙烯(2-氯乙基)醚

CAS 110-75-8 MFCD00000973

化学结构图

110-75-8
SMILES: C=COCCCl

化学属性

Mol. FormulaC4H7ClO
Mol. Weight106.55
Refractive index1.4370 to 1.4390
Boiling Point108°C
Density1.048 g/mL at 25 °C(lit.)
Vapor Pressure760 mmHg ( 109 °C)
Flash Point27°C(lit.)
Melting Point-70°C
Solubility微溶于水。

别名和识别编码

Chemical NameVinyl(2-Chloroethyl)Ether
CAS Number110-75-8
PubChem Substance ID87565347
EC Number203-799-6
Beilstein Registry Number1(2)473
MDL NumberMFCD00000973
Reaxys-RN773787
Merck Number2139
Synonym (2-Chlorethyl)-vinylether (2-chloro-ethyl)-vinyl ether (2-chloroethoxy)-ethen 1-Chloro-2-vinyloxyethane 2-CHLOROETHYL VINYL ETHER 2-Chlorethoxyethe 2-Chlorethyl vinyl ether 2-Chloroethyl vinyl ether 2-Chloroethyl vinyl ether, for epa method 601 2-Chloroethyl-vinyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation乙烯(2-氯乙基)醚
Wiswesser Line NotationG2O1U1
LabNetwork Molecule IDLN00239119
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分类

  • {SNA} Chemical Synthesis, Monomers, Others, Polymer Science, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents, Vinyl Ethers, 材料科学
  • {SNA} Separate Source
  • {uni_hamburg} no charge; ether; 1fragment
  • Alphabetic, Analytical Standards, Analytical/Chromatography, C

产品应用

  • 用于聚合物单体,药品及纤维素酯的制造

相关文献及参考

  • Merck:2139
  • Short: II/5
  • Short: III/35E
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,Xn,T F,Xn F;Xn
RTECSKN6300000
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
Signal word Danger {} {} {} {} {} {} {} {TCI}
UN Number UN 1992 3/PG 2 1992
Storage condition 0-10 储存温度2-8℃ 0-10°C Refrigerator
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Hazard Class3/6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,343,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 210 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 11/15/1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 11/15/1971

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,108,1952

其他信息

  • TCI Shanghai:2-氯乙基乙烯醚(含稳定剂甲基氧氢醌和三乙醇胺) 2-Chloroethyl Vinyl Ether (stabilized with MEHQ + Triethanolamine),>;97.0%(GC)(110-75-8)
  • 蒸气压:760 mm Hg ( 109 °C)
  • 灭火剂:干粉、干砂、干石粉、二氧化碳、泡沫、1211灭火剂
  • 毒性分级:高毒
  • 用途一:用于聚合物单体,药品及纤维素酯的制造
  • Sigma Aldrich:110-75-8(sigmaaldrich)
  • MOL 文件:110-75-8.mol
  • 爆炸物危险特性:在空气中暴露可能产生过氧化物, 积累爆炸
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 火场产生有毒氯化物烟雾
  • MSDS 信息:乙烯-2-氯乙醚(110-75-8).msds
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 无色至淡黄色液体,微溶于水。
  • 外观性质:液体。
  • Acros Organics:乙烯(2-氯乙基)醚 2-Chloroethyl vinyl ether, ca. 95%(110-75-8)
  • 2-氯乙基乙烯基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0174 2-氯乙基乙烯醚(含稳定剂MEHQ和三乙醇胺) 2-Chloroethyl Vinyl Ether (stabilized with MEHQ + Triethanolamine) 500ML 5130元 2014/06/02 C0174 2-氯乙基乙烯醚(含稳定剂MEHQ和三乙醇胺) 2-Chloroethyl Vinyl Ether (stabilized with MEHQ + Triethanolamine) 25ML 637元 2010/06/21 149431000 2-氯乙基乙烯基醚 2-Chloroethyl vinyl ether ca. 95% 100 GR 3018元
  • 急性毒性:口服- 大鼠 LD50: 250 毫克/ 公斤; 吸入- 大鼠 LCL0: 250 PPM/ 4小时
  • 刺激数据:皮肤- 兔子 525 毫克 重度; 眼- 兔子 500 毫克/ 24小时 轻度
  • 图谱信息:2-氯乙基乙烯基醚(110-75-8)质谱(MS) 2-氯乙基乙烯基醚(110-75-8)核磁图( 13 CNMR) 2-氯乙基乙烯基醚(110-75-8)红外图谱(IR1) 2-氯乙基乙烯基醚(110-75-8)Raman光谱
  • 类别:易燃液体

系列性分类


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