2-Chloroethyl Ethyl Sulfide 2-氯乙基乙基硫醚

CAS 693-07-2 MFCD00000979

化学结构图

693-07-2
SMILES: CCSCCCl

化学属性

Mol. FormulaC4H9ClS
Mol. Weight125
Refractive index1.4860 to 1.4900
Boiling Point156-157
Density1.07
Flash Point52°C(lit.)
Solubility不溶

别名和识别编码

Chemical Name2-Chloroethyl Ethyl Sulfide
CAS Number693-07-2
Alfabeta NameCHLOROETHYLTHIOETHANE 12()---
MDL NumberMFCD00000979
PubChem Substance ID12733
EC Number211-742-1
Beilstein Registry Number635672
Reaxys-RN635672
Synonym 1-Chloro-2-(ethylsulfanyl)ethane 1-Chloro-2-(ethylthio)ethane 1-chloro-2-(ethylthio)-ethan 1-chloro-2-(ethylthio)ethane 1-chloro-2-ethylsulfanyl-ethane 1-chloro-3-thiapentane 2-CHLOROETHYL ETHYL SULFIDE 2-CHLOROETHYLETHYLSULPHIDE 2-Chlordiethylsulfid 2-Chloroethyl ethyl sulfide 2-Chloroethyl ethyl thioether 2-Ethylthioethyl chloride 2-chlorodiethyl sulfide 2-chloroethyl ethyl sulfide 2-chloroethyl ethyl sulphide 2-chloroethylethylthioether CEES Ethane, 1-c Ethyl-2-chlorethylsulfid Half-mustard gas beta-ethylmerkaptoethylchlorid(czech) ethane,1-chloro-2-(ethylthio)- ethyl (2-chloro-ethyl) sulfide ethyl-(2-chloro-ethyl)-sulfide {hazar
Chemical Name Translation2-氯乙基乙基硫醚
Wiswesser Line NotationG2S2
LabNetwork Molecule IDLN00226089
InChIInChI=1S/C4H9ClS/c1-2-6-4-3-5/h2-4H2,1H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds
  • {uni_hamburg} no charge; sulfide; 1fragment
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds

产品应用

  • 医药中间体。

相关文献及参考

  • Short: IV/18B
  • Short: III/38B
  • Beilstein:1,349
  • Short: IV/20A
  • Short: IV/16

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 3 T Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSWQ3250000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R23/24 Toxic by inhalation and in contact with skin 吸入及皮肤接触都有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R45 May cause cancer 可能致癌
UN Number 1992
Storage condition 0-10 密封保存 0-10°C 0-6°C
Packing GroupIII
Hazard Class3/6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 252 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku,"
   Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu
   Praha, Czechoslovakia, 1972  Volume(issue)/page/year: -,170,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB158-507

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 5 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 13,19,1971

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,257,1975

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,257,1975

其他信息

  • 类别:有毒物质
  • 急性毒性:口服-大鼠 LD50: 252 毫克/公斤; 皮下-小鼠 LDL0: 25 毫克/公斤
  • 毒性分级:高毒
  • Sigma Aldrich:693-07-2(sigmaaldrich)
  • TCI Shanghai:2-氯乙基乙硫醚 2-Chloroethyl Ethyl Sulfide,>;97.0%(GC)(693-07-2)
  • 2-氯乙基乙基硫醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0938 2-氯乙基乙硫醚 2-Chloroethyl Ethyl Sulfide 5ML 378元 2014/06/02 C0938 2-氯乙基乙硫醚 2-Chloroethyl Ethyl Sulfide 25ML 1100元 2010/06/21 221970050 2-氯乙基乙基硫醚 2-Chloroethyl ethyl sulfide 95% 5 GR 369元
  • 刺激数据:皮肤-兔 500 毫克/24小时 重度; 眼睛-兔 0.25 毫克/24小时 重度
  • 储运特性:库房低温通风干燥; 与食品原料分开存放
  • 灭火剂:水, 二氧化碳, 泡沫, 沙土
  • Acros Organics:2-氯乙基乙基硫醚 2-Chloroethyl ethyl sulfide, 95%(693-07-2)
  • 图谱信息:2-氯乙基乙基硫醚(693-07-2)质谱(MS) 2-氯乙基乙基硫醚(693-07-2)红外图谱(IR1)
  • 不溶于水
  • 可燃性危险特性:可燃; 火场释放有毒氯化物, 硫氧化物气体
  • MOL 文件:693-07-2.mol

系列性分类


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