1,4-Diiodobenzene 1,4-二碘苯

CAS 624-38-4 MFCD00001054

化学结构图

624-38-4
SMILES: Ic1ccc(I)cc1

化学属性

Mol. FormulaC6H4I2
Mol. Weight329.91
Density2.469
Boiling Point285°C at 760 mmHg
Melting Point131-133°C
TSCAYes
Refractive index1.6212
Stability对光敏感
Flash Point285°C
Appearance 无色或微黄色片状结晶。熔点131-132℃,沸点285℃(升华)。易溶于乙醚,溶于乙醇,不溶于水。

别名和识别编码

Chemical Name1,4-Diiodobenzene
CAS Number624-38-4
Alfabeta NameDIIODOBENZENE 14-,
MDL NumberMFCD00001054
Synonym 1,4-Diiodobenzene {LY} 1,4-Diiodobenzene {} {LY} 1,4-Diiodobenzene {} {} {LY} 1,4-Diiodobenzene {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number210-842-2
Beilstein Registry Number1904546
PubChem Substance ID12208
Reaxys-RN1904546
Chemical Name Translation1,4-二碘苯
InChIKeyLFMWZTSOMGDDJU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00175671
InChIInChI=1S/C6H4I2/c7-5-1-2-6(8)4-3-5/h1-4H
Canonical SMILESC1=CC(=CC=C1I)I
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分类

  • {SNA} Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 用于有机合成。

相关文献及参考

  • Short: II/27B
  • Beilstein:5,227
  • Short: III/20c
  • Undergoes Pd-catalyzed carbonylative cross-coupling with arylboronic acids, e.g. 4-Methyl­benzeneboronic acid, A13347, to give diketones; (cf. trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491 and Appendix 5): Tetrahedron Lett., 34, 7595 (1993); J. Org. Chem., 63, 4726 (1998):

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Light Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Hazard Codes Xi

其他信息

  • 用途一:主要作为生物制药中的医药中间体
  • MSDS 信息:1,4-Diiodobenzene(624-38-4).msds
  • 方法一:由对碘苯胺经重氮化、置换而得。另一种制备方法是用对苯二胺盐酸盐重氮化,再与碘化钾进行置换反应。
  • 下游产品:对三联苯
  • Sigma Aldrich:624-38-4(sigmaaldrich)
  • F:8
  • MOL 文件:624-38-4.mol
  • 图谱信息:1,4-二碘苯(624-38-4)核磁图( 13 CNMR) 1,4-二碘苯(624-38-4)红外图谱(IR1) 1,4-二碘苯(624-38-4)核磁图( 1 HNMR) 1,4-二碘苯(624-38-4)红外图谱(IR2) 1,4-二碘苯(624-38-4)质谱(MS) 1,4-二碘苯(624-38-4)红外图谱(IR3)
  • 用途二:用于有机合成。
  • 海关编码:29036990
  • Acros Organics:1,4-二碘苯 1,4-Diiodobenzene, 98%(624-38-4)
  • 易溶于乙醚,溶于乙醇,不溶于水。
  • TCI Shanghai:1,4-二碘苯 1,4-Diiodobenzene(624-38-4)
  • 1,4-二碘苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0608 1,4-二碘苯 1,4-Diiodobenzene 5G 247元 2014/06/02 D0608 1,4-二碘苯 1,4-Diiodobenzene 25G 746元 2010/06/21 185970500 1,4-二碘苯 1,4-Diiodobenzene 98% 50 GR 999元
  • Alfa Aesar:1,4-二碘苯,98% 1,4-Diiodobenzene, 98%(624-38-4)
  • 敏感性:Light Sensitive

系列性分类


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