ALLYL IODIDE 丙烯酰碘

CAS 556-56-9 MFCD00001094

化学结构图

556-56-9
SMILES: C=CCI

化学属性

Mol. FormulaC3H5I
Mol. Weight168
Refractive index1.5520 to 1.5560
Boiling Point102°C
Density1.837 g/mL at 25 °C(lit.)
Flash Point16°C(lit.)
TSCAYes
Melting Point-99°C
Solubility不溶于水,可混溶于乙醇、乙醚。
Stability对光敏感; 对空气敏感; 对热敏感

别名和识别编码

Chemical NameALLYL IODIDE
Synonym Allyljodid 3-Iodpropen 3-IODOPROPENE 碘代烯丙基 3-碘丙烯;3-碘-1-丙烯 烯丙基碘 3-Jodpropen 3-Iodopropene 3-Jod-1-propen 2-Propenyliodide 3-iodo-1-propen 3-Iod-1-propen 丙烯酰碘 3-iodopropene 3-Iodo-1-propene 1-Propene, 3-iodo- 3-Iodopropylene 3-iodpropene allyl iodide 3-碘丙烯 3-iodo-prop-1-ene propene, 3-iodo- 3-IODO-1-PROPENE 3-iodo-1-propene 3-IODOPROPYLENE Allyl iodide 2-Propenyl iodide 3-碘代-1-丙烯 3-碘-1-丙烯 1-propene, 3-iodo- 碘化烯丙基 2-Propene, 1-iodo 3-iodopropylene ALLYL IODIDE, STAB. 碘丙烯 ALLYL IODIDE Propene, 3-iodo- CH2CHCH2I 1-propene,3-iodo- propene,3-iodo- 3-碘丙烯, 97+%, 铜作稳定剂 Allyliodid 3-iodo-propen 3-iodo-propene
MDL NumberMFCD00001094
CAS Number556-56-9
PubChem Substance ID87571474
EC Number209-130-4
Beilstein Registry Number1,202
Merck Number294
Reaxys-RN1697594
Chemical Name Translation丙烯酰碘
Wiswesser Line NotationI2U1
LabNetwork Molecule IDLN00225253
InChIInChI=1S/C3H5I/c1-2-3-4/h2H,1,3H2
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分类

  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于环丙烯的顺式双向烯丙基化反应。

相关文献及参考

  • Merck:14,294
  • Short: II/14a
  • Short: III/38B
  • Short: II/25C
  • Precursor, by reaction with In metal powder, of allylindium reagents which add to alkynes to give 1,4-dienes: J. Org. Chem., 62, 2318 (1997). Allylindiums add to cyclopropenes at the more substituted C atom to give allylcyclopropanes: Tetrahedron Lett., 39, 6317 (1998).
  • Merck:14,294 Beilstein:1,202

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUD0450000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P304+P340+P310
  • P403+P235
  • P241+P242+P243
  • P303+P361+P353+P310+P363
Signal word Danger
Packing GroupII
UN Number UN1723 UN 1723 3/PG 2 1723
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R10 Flammable 易燃
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Storage condition Light Sensitive 2-8°C 0-10°C 储存温度2-8°C 0-10
Hazard Codes F,C C C,T,F
Hazard Class3/8
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Lungs, Thorax, or Respiration - cyanosis
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0570938

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   29,993,1980

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 50 umol/L
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   20,263,1983

Restrict 危险品

其他信息

  • 灭火剂:泡沫、雾状水、干粉、砂土
  • 毒性分级:剧毒
  • Acros Organics:烯丙基碘 Allyl iodide, stabilized, 98%(556-56-9)
  • 可燃性危险特性:明火、高热可燃;与氧化剂反应; 燃烧产生有毒碘化物烟雾
  • 下游产品:异硫氰酸烯丙酯
  • 用途一:用于环丙烯的顺式双向烯丙基化反应。
  • TCI Shanghai:3-碘-1-丙烯(含稳定剂铜屑) Allyl Iodide (stabilized with Copper chip),>;98.0%(GC)(556-56-9)
  • TSCA:T
  • 图谱信息:丙烯酰碘(556-56-9)核磁图( 13 CNMR) 丙烯酰碘(556-56-9)核磁图( 1 HNMR) 丙烯酰碘(556-56-9)质谱(MS) 丙烯酰碘(556-56-9)红外图谱(IR1)
  • F:8-13
  • 外观性质:黄色液体, 有刺激性气味。
  • 敏感性:Air & Light Sensitive
  • 实际上不溶于水,和醇、氯仿和醚混溶。
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 急性毒性:口服- 小鼠 LD50: 10 毫克/ 公斤
  • Sigma Aldrich:556-56-9(sigmaaldrich)
  • 类别:有毒物品
  • 丙烯酰碘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0070 烯丙基碘(含稳定剂铜屑) Allyl Iodide (stabilized with Copper chip) 25G 870元 2010/06/21 218540250 丙烯酰碘 Allyl iodide 98%, stabilized 25 ML 827元 2010/06/21 218541000 丙烯酰碘 Allyl iodide 98%, stabilized 100 ML 2172元
  • MSDS 信息:碘丙烯(556-56-9).msds
  • MOL 文件:556-56-9.mol
  • Alfa Aesar:3-碘丙烯,97+%,铜作稳定剂 Allyl iodide, 97+%, stab. with copper(556-56-9)

系列性分类


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