9-Fluorenemethanol, 99% 9-芴甲醇

CAS 24324-17-2 MFCD00001139

化学结构图

24324-17-2
SMILES: OCC1c2ccccc2-c2ccccc21

化学属性

Mol. FormulaC14H12O
Mol. Weight196.25
Melting Point105-107°C
TSCAYes
Density1.422
Boiling Point363.9°C at 760 mmHg

别名和识别编码

Chemical Name9-Fluorenemethanol, 99%
CAS Number24324-17-2
Alfabeta NameFLUORENEMETHANOL 9-
MDL NumberMFCD00001139
Synonym 9-Fluorenylmethanol {LY} 9-Fluorenylmethanol {} {LY} 9-Fluorenylmethanol {} {} {LY} 9-Fluorenylmethanol {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluoreny
PubChem Substance ID87569980
Beilstein Registry Number6(3)3507
EC Number246-167-5
Reaxys-RN2330017
Chemical Name Translation9-芴甲醇
InChIKeyXXSCONYSQQLHTH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173075
Canonical SMILESC1=CC=CC3=C1C2=CC=CC=C2C3CO
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分类

  • {SNA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {SA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

产品应用

  • 在合成脱氧核糖核苷酸时磷酸酯的保护基团；羧基保护基团。

相关文献及参考

  • Reagent for protection of carboxyl groups as their 9-fluorenylmethyl (Fm) esters, which improve solubility of the molecule in organic solvents. Fm esters can be formed, e.g. by the DCC-DMAP method: Tetrahedron Lett., 24, 281 (1983), or by imidazole-catalyzed transesterification of active esters of N-protected amino acids: Int. J. Pept. Prot. Res., 21, 196 (1983). Cleavage is by hydrogenolysis. See Appendix 6.
  • Can also be used to protect phosphate groups in oligonucleotide synthesis: J. Chem. Soc., Chem. Commun., 803 (1973).
  • Beilstein:6(3)3507

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Indazoles 吲唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C9 to C10 - Alcohols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C11 to C30+ - Alcohols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Fluorenes & Fluorenones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols
  6. C7 to C8

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