Anthrone 蒽酮

CAS 90-44-8 MFCD00001187

化学结构图

90-44-8
SMILES: O=C1c2ccccc2Cc2ccccc21

化学属性

Mol. FormulaC14H10O
Mol. Weight194.23
Melting Point154-157 °C
SolubilitySoluble in ethyl acetate (20 mg/ml), water (0.5 mg/ml at 20 °C), acetone, ethanol (very slightly), and ether (slightly).
TSCAYes
Boiling Point721 °C at 760 mmHg
Density1.194
Stability对光和空气敏感
Appearance 无色针状结晶体。熔点为155℃，溶于大多数有机溶剂和热氢氧化钠溶液，不溶于水。无荧光，所出现的荧光是由蒽酚所致。

别名和识别编码

Chemical NameAnthrone
Synonym Anthrone {LY} Anthrone {} {LY} Anthrone {} {} {LY} Anthrone {} {} {} {LY} Anthrone {} {} {} {} {LY} Anthrone {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Anthrone
MDL NumberMFCD00001187
PubChem Substance ID87562120
Beilstein Registry Number7,473
CAS Number90-44-8
EC Number201-994-0
Reaxys-RN1910173
Merck Number691
Chemical Name Translation蒽酮
LabNetwork Molecule IDLN00008128
InChIInChI=1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2
Canonical SMILESO=C1C2=C(C=CC=C2)CC3=CC=CC=C13
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分类

  • {SNA} A, Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学
  • {SNA} A, AM to AQ, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Life Sciences Standards, Natural Compounds
  • {SNA} Additional Standards, Analytical Standards, Chromatography, Life Sciences Standards, Natural Compounds, 分析/色谱
  • Analytical Reagents, Analytical/Chromatography,

产品应用

  • An aromatic hydrocarbon used to determine hydrocarbons.

相关文献及参考

  • Short: II/27B
  • Merck: 14,691 Beilstein:7,473
  • Merck: 14,691
  • Merck 14 ,691
  • Short: II/3

安全信息

GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
WGK Germany3
RTECSCB8925500
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Light Sensitive Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 60 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 157,149,1985

其他信息

  • 不产生荧光，不溶于水，溶于热NaOH 溶液、浓硫酸、乙醇、苯、丙酮等大多数有机溶剂。
  • 可燃性危险特性:可燃; 燃烧产生刺激烟雾
  • 储运特性:库房通风低温干燥
  • 上游原料:蒽醌 --> 锡粒
  • Alfa Aesar:蒽酮,ACS Anthrone, ACS(90-44-8)
  • Sigma Aldrich:90-44-8(sigmaaldrich)
  • 用途一:该品用于有机合成，用糖和动物体液中淀粉的比色测定。
  • F:8
  • 下游产品:9-乙烯基蒽 --> 苯并蒽酮 --> 溶剂红 52 --> 9-苯基蒽 --> 溶剂红 149 --> 还原黑29
  • 方法一:由蒽醌经下列反应得到。将104g蒽醌、100g锡粒、750ml冰醋酸混合加热至沸，再逐次加入浓盐酸250ml（相对密度为1.19），约2h加完，此时蒽醌应全部溶于反应液中，否则，需补加锡粒和盐酸。再回流1.5h，脱色过滤，滤液用100ml水稀释，冷却至10℃，析出蒽酮结晶，过滤，用水洗使pH=7而得粗晶，干重80g。粗品可用丙酮或苯和石油醚（3：1）混合液重结晶，可得熔点为154-155℃的蒽酮约60g。
  • 用途二:快速测定液体中糖分、肝脏组织中的动物淀粉，有机合成。
  • 蒽酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30015014 蒽酮;9,10-二氢-9-氧蒽 25g 56元 2011/04/16 A0509 蒽酮 Anthrone 25G 570元 2010/06/21 104961000 蒽酮 Anthrone , for analysis ACS 100 GR 1737元
  • TCI Shanghai:蒽酮 Anthrone(90-44-8)
  • MOL 文件:90-44-8.mol
  • Acros Organics:蒽酮 Anthrone, for analysis ACS(90-44-8)
  • 图谱信息:蒽酮(90-44-8)质谱(MS) 蒽酮(90-44-8)红外图谱(IR3) 蒽酮(90-44-8)红外图谱(IR2) 蒽酮(90-44-8)核磁图( 13 CNMR) 蒽酮(90-44-8)核磁图( 1 HNMR) 蒽酮(90-44-8)红外图谱(IR1)
  • 敏感性:Light Sensitive
  • Anthrone is a trycyclic aromatic hydrocarbon that can be used to determine hydrocarbons using a colorimetric method. It can help estimate carbohydrates in yeast and plant extracts.
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Application Specific Reagents - Analytical Reagents
  4. Fatty Acid Analysis in Blood - Application Specific Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12

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