2-Methylanthraquinone 2-甲基蒽醌

CAS 84-54-8 MFCD00001235

化学结构图

84-54-8
SMILES: Cc1ccc2c(c1)C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC15H10O2
Mol. Weight222
Boiling Point236-238
Melting Point175-178
Flash Point209°(408°F)
TSCAYes
Appearance 黄色晶体。 不溶于水，溶于乙醇、乙醚、苯和乙酸乙酯。
Solubility不溶于水，溶于乙醇、乙醚、苯和乙酸乙酯。

别名和识别编码

Chemical Name2-Methylanthraquinone
CAS Number84-54-8
PubChem Substance ID87572255
EC Number201-539-6
Beilstein Registry Number2050523
MDL NumberMFCD00001235
Reaxys-RN2050523
Merck Number6021
Synonym 2-甲蒽醌 β-Methylanthrachinon 2-Methylanthra-9,10-quinone 2-methyl-9,10-anthraquinone 2-methyl-9,10(9H,10H)-anthracenedione 柚木醌 2-甲基-9,10-蒽二酮;β-甲基蒽醌;2-甲蒽醌 anthraquinone,2-methyl- Methylanthraquinone Tectochinon 2-METHYL AQ METHYLANTHRAQUINONE, 2- 2-Methylanthracenedione Anthraquinone, 2-methyl- Techtoquinone β-甲基蒽醌 9,10-Anthracenedione,2-methyl- 2-甲基蒽醌,97% 2-Methylanthracene-9,10-dione LABOTEST-BB LT00159669 2-MAQ beta-Methylanthraquinone 2-METHYLANTHRAQUINONE 2-Methylanthrapuinone Methylanthraquinone; Tectoquinone; 2-Methyl-9,10-anthracenedione 10-蒽二酮 β-Methylanthraquinone 2-Methyl-anthraquinone 9,10-Antracenedione, 2-methyl- 2-Methyl-9,10-anthracenedione -Methylanthranpuinone 2-Methylanthrachinon BETA-甲基恩奎酮 2-甲基-9 2-甲基蒽醌 2-methylanthraquinone 9,10-Anthracenedione, 2-methyl- anthraquinone, 2-methyl- TECTOQUINONE Tectoquinone 2-甲基-9,10-蒽二酮 2-甲基蒽醌, 97% 2-methyl-10-anthracenedione
Chemical Name Translation2-甲基蒽醌
LabNetwork Molecule IDLN00193466
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分类

  • {SNA} Building Blocks, C15 to C38,
  • Bioactive Small Molecules, Building Blocks, C15 to C38, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, M, Organic Building Blocks
  • {SNA} Bioactive Small Molecules, Building Blocks, C15 to C38, Carbonyl Compounds, Chemical Synthesis, Ketones, M, Organic Building Blocks, 细胞生物学
  • {SNA} Bioactive Small Molecules, Building Blocks, C15 to C38, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones,
  • {SNA} Building Blocks,

相关文献及参考

  • Merck 14 ,6021
  • Beil. 7 ,IV,2574
  • FT-IR 2 (2), 2491:D / FT-IR 1 (2), 84:D / FT-NMR 1 (2), 912:C / IR-Spectra (2), 786:D / IR-Spectra (3), 899:B / NMR-Reference 2 (2), 89:B / RegBook 1 (2), 1687:I / Structure Index 1 , 267:B:8
  • Short: II/3 Title: Luminescence of Organic Substances Author: Schmillen, A.; Legler, R. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/3 Year: 1967 ISBN: 3-540-03895-7 ISBN: 978-3-540-03895-5 Internet Resource: DOI:10.1007/b86158 RefComment: 270 figs., VIII, 416 pages. Hardcover Abstract: For more than 1000 luminescent organic substances the most important data are represented as wave numbers of absorption and emission bands, decay times and quantum efficiencies. Additional tables contain further information for restricted groups of substances (figures on typical spectra, wave numbers of sharp single bands, influence of surrounding molecules, etc.).
  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and inter

安全信息

WGK Germany3
Hazard Codes N Xi,N
Personal Protective Equipment Eyeshields, Gloves
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R51/53
UN Number UN 3077 9/PG 3
GHS Symbol
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。

其他信息

  • 用途二:用于有机合成原料、合成染料、光敏树脂的光敏剂。
  • 上游原料:三氯化铝 --> 发烟硫酸 --> 苯酐 --> 2-(对甲苯甲酰基)苯甲酸
  • MOL 文件:84-54-8.mol
  • 下游产品:大黄素 --> 还原橙 9 --> 酸性兰47
  • Sigma Aldrich:84-54-8(sigmaaldrich)
  • 用途三:可作染料中间体，感光树脂的感光剂，有机合成原料。
  • 图谱信息:2-甲基蒽醌(84-54-8)质谱(MS) 2-甲基蒽醌(84-54-8)核磁图( 1 HNMR) 2-甲基蒽醌(84-54-8)红外图谱(IR2) 2-甲基蒽醌(84-54-8)核磁图( 13 CNMR) 2-甲基蒽醌(84-54-8)红外图谱(IR1)
  • Alfa Aesar:2-甲基蒽醌,97% 2-Methylanthraquinone, 97%(84-54-8)
  • Hazard Note:Irritant
  • 方法一:将甲苯与无水三氯化铝加热，控制温度在45-50℃，在外部冷却下加入邻苯二甲酸酐，混合物保温至反应完全。将反应混合物倒入10%硫酸水溶液中，含产品的浆状物经水洗、分层、分离。含产品的溶剂层与5%碳酸钠溶液混合、过滤、洗涤、干燥而得2-（对甲苯酰）苯甲酸，然后与发烟硫酸在115℃加热1h进行闭环，将产物倾入冷水中，过滤、水洗、干燥而得。
  • MSDS 信息:Methylanthraquinone(84-54-8).msds
  • TCI Shanghai:2-甲基蒽醌 2-Methylanthraquinone,>;99.0%(GC)(84-54-8)
  • 2-甲基蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010028 2-甲基蒽醌;β-甲基蒽醌 5g 75元 2011/04/16 M0156 2-甲基蒽醌 2-Methylanthraquinone 500G 2740元 2011/04/16 M0156 2-甲基蒽醌 2-Methylanthraquinone 25G 328元
  • 海关编码:29146990
  • 用途一:用于生产高级染料及中间体
  • Acros Organics:2-甲基蒽醌 2-Methylanthraquinone, 94%(84-54-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C15 to C38 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Anthraquinones

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