(+)-α-Pinene (+)-α-蒎烯

CAS 7785-70-8 MFCD00001346

化学结构图

7785-70-8
SMILES: CC1=CC[C@@H]2C[C@H]1C2(C)C

化学属性

Mol. FormulaC10H16
Mol. Weight136.23
Refractive index1.4650 to 1.4670
Boiling Point155-156°C at 760 mmHg
Density0.858
Melting Point-62°C
Flash Point33°C
TSCAYes
Autoignition Point491 °F

别名和识别编码

Chemical Name(+)-α-Pinene
Synonym (1R)-α-Pinene {LY} (1R)-α-Pinene {} {LY} (1R)-α-Pinene {} {} {LY} (1R)-α-Pinene {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (1R)-α-Pinene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number2038653
CAS Number7785-70-8
PubChem Substance ID82227
EC Number232-087-8
MDL NumberMFCD00001346
Reaxys-RN13246646
Merck Number7445
Chemical Name Translation(+)-α-蒎烯
LabNetwork Molecule IDLN00195589
InChIInChI=1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9-/m1/s1
Canonical SMILESCC1(C)[C@]2([H])CC=C(C)[C@@]1([H])C2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, All Alphabetically Sorted, Analytical Standards, Analytical/Chromatography, Chromatography, Flavors and Fragrances, Food & Beverage Standards, Food Products & Beverages, Herbs & Spices, Life Sciences Standards, M-R, Natural Compounds, Natural Terpene Standards, P, PER - POLA, Rosemary, Substance Classification, Terpene
  • {SNA} A-D, Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O-P
  • {SNA} Alphabetical Index of Analytical Sta

产品应用

  • 用于制备手性硼氢化试剂。

相关文献及参考

  • Forms a chiral adduct with diborane, useful for asymmetric hydroborations with high optical yields: J. Am. Chem. Soc., 99, 5514 (1977). Recrystallization of the borane adduct can be used to obtain a pure single diastereomer: J. Org. Chem., 49, 945 (1984). For reviews of the synthesis of pure enantiomers via chiral organoboranes, see: Acc. Chem. Res., 21, 287 (1988); and of asymmetric reduction with chiral organoboranes based on ɑ-pinene: Acc. Chem. Res., 25, 16 (1992).
  • Short: III/38B
  • Short: IV/16
  • Short: I

安全信息

GHS Symbol
WGK Germany3
Hazard Codes
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number UN2368
RTECSDT7000000
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupIII
Hazard Class3
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storag

其他信息

  • Sigma Aldrich:7785-70-8(sigmaaldrich)
  • 蒎烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1099 (1R)-(+)-α-蒎烯 (1R)-(+)-alpha-Pinene 25ML 222元 2014/06/02 P1099 (1R)-(+)-α-蒎烯 (1R)-(+)-alpha-Pinene 500ML 1610元 2010/06/21 131261000 蒎烯 (1R)-(+)-alpha-Pinene 98%, 80% ee 100 GR 675元
  • Acros Organics:(1R)-(+)-alpha-蒎烯 (1R)-(+)-alpha-Pinene, 80% ee, 98%(7785-70-8)
  • Alfa Aesar:(+)-α-蒎烯,98% (+)-alpha-Pinene, 98%(7785-70-8)
  • 图谱信息:蒎烯(7785-70-8)质谱(MS) 蒎烯(7785-70-8)核磁图( 1 HNMR) 蒎烯(7785-70-8)核磁图( 13 CNMR) 蒎烯(7785-70-8)红外图谱(IR1)
  • TCI Shanghai:(1R)-(+)-α-蒎烯 (1R)-(+)-alpha-Pinene,>;95.0%(GC)(7785-70-8)
  • 下游产品:(1S,2S,3R,5S)-(+)-2,3-蒎烷二醇
  • 用途一:药品/化学原料药和中间体,如制备原料药孟鲁司特钠(顺尔宁)以及恩替卡韦的中间体 ;该产品是光学拆分剂,还可应用于其他领域。
  • F:10
  • 检测方法:GC,Rotation,Moisture
  • MOL 文件:7785-70-8.mol

系列性分类


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