1-Methylcyclopentene 1-甲基环戊烯
CAS 693-89-0 MFCD00001397
化学结构图
SMILES: CC1=CCCC1
化学属性
| Mol. Formula | C6H10 |
|---|---|
| Mol. Weight | 82 |
| Boiling Point | 75°C |
| Density | 0.78 g/mL at 25 °C(lit.) |
| Refractive index | 1.4300 to 1.4340 |
| Flash Point | -19°C(lit.) |
| TSCA | No |
| Melting Point | -142° |
| Solubility | 不溶于水，溶于乙醇、乙醚。 |
别名和识别编码
| Chemical Name | 1-Methylcyclopentene |
|---|---|
| CAS Number | 693-89-0 |
| PubChem Substance ID | 12746 |
| EC Number | 211-762-0 |
| Beilstein Registry Number | 5,64 |
| MDL Number | MFCD00001397 |
| Synonym | 甲基环戊烯 1-Methylcyclpentene METHYL-CYCLOPENTENE 1-Methylcyclopentene,96% 1-甲基-环戊烷 cyclopentene,1-methyl- 1-Cyclopentene, 1-methyl 1-甲基环戊烯 1-methyl-cyclopentene 1-甲基-环戊烯 1-Methyl-1-cyclopentane 1-METHYL-1-CYCLOPENTENE 1-Methylcyclopentene-1 1-甲基环戊烯, 98% cyclopentene, 1-methyl- 1-甲基环戊烯,96% 1-Methyl-1-cyclopentene 1-methyl-1-cyclopentene Cyc1opentene,l-methyl- 1-METHYLCYCLOPENTENE 1-甲基-1-环戊烯 1-methylcyclopentene |
| Reaxys-RN | 1900640 |
| Chemical Name Translation | 1-甲基环戊烯 |
| LabNetwork Molecule ID | LN00222402 |
| InChI | InChI=1S/C6H10/c1-6-4-2-3-5-6/h4H,2-3,5H2,1H3 |
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分类
- {SNA} Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks
- Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; alicycle; 5ring; 1fragment
相关文献及参考
- Short: III/38B
- Short: IV/16
- Short: IV/18B
- Undergoes [2+2] cycloaddition with dichloroketene (generated in situ from trichloroacetyl chloride) to give a dichlorobicylo[3.2.0]heptanone derivative. Treatment with n-BuLi, then acetic anhydride gives a ß-chloroenol acetate, RuO4 cleavage of which gives the cis-dicarboxylic acid: Org. Synth. Coll., 8, 377 (1993):
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P303+P361+P353
- P331 Do NOT induce vomiting.. 不要催吐。
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R11 Highly flammable 非常易燃
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- S7 Keep container tightly closed 保存在严格密闭容器中；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
其他信息
- F:10-23
- 海关编码:29021990
- TCI Shanghai:1-甲基-1-环戊烯 1-Methyl-1-cyclopentene,>;98.0%(GC)(693-89-0)
- Alfa Aesar:1-甲基环戊烯,98% 1-Methylcyclopentene, 98%(693-89-0)
- 图谱信息:1-甲基环戊烯(693-89-0)核磁图( 1 HNMR) 1-甲基环戊烯(693-89-0)红外图谱(IR1) 1-甲基环戊烯(693-89-0)质谱(MS) 1-甲基环戊烯(693-89-0)Raman光谱 1-甲基环戊烯(693-89-0)核磁图( 13 CNMR)
- MSDS 信息:1-甲基环戊烯(693-89-0).msds
- 外观性质:无色液体。
- Acros Organics:1-甲基-1-环戊烯 1-Methyl-1-cyclopentene, 96%(693-89-0)
- MOL 文件:693-89-0.mol
- 1-甲基环戊烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80083380 1－甲基－1－环戊烯 5ml 69.3元 2011/04/16 M0727 1-甲基-1-环戊烯 1-Methyl-1-cyclopentene 5ML 727元 2010/06/21 126700250 1-甲基环戊烯 1-Methyl-1-cyclopentene 96% 25 ML 2693元
- Sigma Aldrich:693-89-0(sigmaaldrich)
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