Bis(cyclopentadienyl)ruthenium(II) 双(环戊二烯)钌

CAS 1287-13-4 MFCD00001442

化学结构图

1287-13-4
SMILES: [CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Ru]

化学属性

Mol. FormulaC10H10Ru
Mol. Weight231.26
Melting Point199.0 to 205.0 deg-C
TSCANo
Stability对空气敏感，对湿度敏感
Appearance light yellow xtl.
Boiling Point275.9 °C at 760 mmHg
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameBis(Cyclopentadienyl)Ruthenium(Ii)
Synonym Bis(cyclopentadienyl)ruthenium(II) {LY} Bis(cyclopentadienyl)ruthenium(II) {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)ruthenium(II) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclop
MDL NumberMFCD00001442
PubChem Substance ID21946302
CAS Number1287-13-4
EC Number215-065-2
Chemical Name Translation双(环戊二烯)钌
InChIKeyBKEJVRMLCVMJLG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00201055
Canonical SMILES[][Ru][].c1cccc1.c2cccc2
InChIInChI=1S/2C5H5.Ru/c2*1-2-4-5-3-1;/h2*1-3H,4H2;/q2*-1;+2
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分类

  • {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Ruthenium Catalysts,
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Ruthenium Catalysts, Vapor Deposition Precursors, 材

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: II/27C Title: Diamagnetic Susceptibility and Magnetic Anisotropy of Organic Compounds Author: Kumar, Mahendra; Gupta, Rajni Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27C Year: 2008 Keyword: diamagnetic susceptibility; magnetic anisotropy; organic compounds ISBN: 978-3-540-44734-4 (print) ISBN: 978-3-540-44736-8 (online) Internet Resource: doi:10.1007/978-3-540-44736-8 RefComment: VIII, 204 p., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics,

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning {} {} {} {} {} {} {} {TCI}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote
Restrict -

其他信息

  • Sigma Aldrich:1287-13-4(sigmaaldrich)
  • 图谱信息:二茂钌(1287-13-4)质谱(MS) 二茂钌(1287-13-4)核磁图( 13 CNMR) 二茂钌(1287-13-4)核磁图( 1 HNMR) 二茂钌(1287-13-4)红外图谱(IR1) 二茂钌(1287-13-4)红外图谱(IR2)
  • Alfa Aesar:双(环戊二烯)钌,Ru43.2%min Bis(cyclopentadienyl)ruthenium, Ru 43.2% min(1287-13-4)
  • Acros Organics:二茂钌 Ruthenocene, 99%(1287-13-4)
  • TCI Shanghai:双(环戊二烯)钌 Ruthenocene(1287-13-4)
  • 二茂钌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 R0078 二茂钌 Ruthenocene 1G 1620元 2010/06/21 419190010 二茂钌 Ruthenocene 99% 1 GR 1434元 2010/05/25 12781 双(环戊二烯)钌 , Ru 43.2% min Bis(cyclopentadienyl)ruthenium, Ru 43.2% min 5g 7938元
  • 敏感性:Air & Moisture Sensitive
  • MOL 文件:1287-13-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Ru Catalysts - Ruthenium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Ru Catalysts - Ruthenium
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Ruthenium - CVD and ALD Precursors by Metal
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Ruthenium
  1. Organometallics for CVD & ALD
  2. Ruthenium
  1. Metallocenes, Derivatives & Cp Precursors
  2. Ruthenium

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