Silane, (1-cyclohexen-1-yloxy)trimethyl- 1-环己烯氧基三甲基硅烷

CAS 6651-36-1 MFCD00001541

化学结构图

6651-36-1
SMILES: C[Si](C)(C)OC1=CCCCC1

化学属性

Mol. FormulaC9H18OSi
Mol. Weight170.32
Refractive index1.4450 to 1.4480
Boiling Point64-65 °C at 15 mmHg
Density0.875 g/mL at 25 °C(lit.)
Flash Point41°C(lit.)
TSCAYes

别名和识别编码

Chemical Name(Cyclohex-1-en-1-yloxy)trimethylsilane
CAS Number6651-36-1
Alfabeta NameTRIMETHYLSILYLOXYCYCLOHEXENE 1()-
MDL NumberMFCD00001541
Synonym 1-Cyclohexenyloxytrimethylsilane {LY} 1-Cyclohexenyloxytrimethylsilane {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID81161
EC Number229-675-1
Beilstein Registry Number1859394
Reaxys-RN1859394
Chemical Name Translation1-环己烯氧基三甲基硅烷
InChIKeySBEMOANGDSSPJY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00160539
Canonical SMILESO(C1=CCCCC1)[Si](C)(C)C
InChIInChI=1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Aldrich MSDS 1 , 519:D / Corp MSDS 1 (1), 969:A / FT-IR 2 (3), 4369:A / FT-NMR 1 (3), 662:A / IR-Spectra (3), 1538:G / IR-Spectra (2), 1316:G / NMR-Reference 2 (2), 991:D / RegBook 1 (2), 2969:G / Structure Index 1 , 470:B:1 / Vapor Phase 3 , 1642:C
  • Silyl enol ethers undergo crossed aldol condensations with aldehydes and ketones: J. Am. Chem. Soc., 96, 7503 (1974); for tabulated results, see: Org. Synth. Coll., 8, 323 (1993):
  • Condensation with aldehydes is also promoted by F-, particularly TBAF: J. Org. Chem., 48, 932 (1983).
  • The Lewis acid-catalyzed condensation with nitroalkenes leads to 1,4-diketones: J. Am. Chem. Soc., 98, 4679 (1976); Org. Synth. Coll, 7, 414 (1990).
  • For reviews of the chemistry of silyl enol ethers, see: Synthesis, 91 (1977); 85 (1983).

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning {} {} {} {} {} {} {TCI}
UN Number 1993 UN 1993 3/PG 3 UN1993
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Risk Statements
  • R10 Flammable 易燃
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupIII
Hazard Codes F
Hazard Class3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；

其他信息

  • Hazard Note:Flammable/Keep Cold/Moisture Sensitive
  • TCI Shanghai:1-(三甲基硅氧基)环己烯 1-(Trimethylsilyloxy)cyclohexene,>;95.0%(GC)(6651-36-1)
  • Sigma Aldrich:6651-36-1(sigmaaldrich)
  • MOL 文件:6651-36-1.mol
  • Alfa Aesar:1-(三甲基硅氧烷)环己烯,99% 1-(Trimethylsiloxy)cyclohexene, 98%(6651-36-1)
  • 敏感性:Moisture Sensitive
  • 1-环己烯氧基三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1556 1-(三甲基硅氧基)环己烯 1-(Trimethylsilyloxy)cyclohexene 25ML 688元 2014/06/02 T1556 1-(三甲基硅氧基)环己烯 1-(Trimethylsilyloxy)cyclohexene 10ML 402元 2010/05/25 A16099 1-(三甲基硅氧烷)环己烯, 99% 1-(Trimethylsiloxy)cyclohexene, 98% 250g 8442元
  • F:10-21
  • 图谱信息:1-环己烯氧基三甲基硅烷(6651-36-1)核磁图( 13 CNMR) 1-环己烯氧基三甲基硅烷(6651-36-1)红外图谱(IR1) 1-环己烯氧基三甲基硅烷(6651-36-1)质谱(MS) 1-环己烯氧基三甲基硅烷(6651-36-1)核磁图( 1 HNMR)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Functional Group 官能团索引
  2. enol ether

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