9-Methyl-5(10)-octaline-1,6-dione (±)-8a-甲基-3,4,8,8a-四氢-1,6(2H,7H)-萘二酮
CAS 20007-72-1 MFCD00001687
化学结构图
SMILES: CC12CCC(=O)C=C1CCCC2=O
化学属性
| Mol. Formula | C11H14O2 |
|---|---|
| Mol. Weight | 178 |
| Melting Point | 47-50 °C (lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | 9-Methyl-5(10)-octaline-1,6-dione |
|---|---|
| Synonym | 魏兰德-米歇尔酮 (±)-9-甲基-5(10)-辛-1,6-二酮 (+/-)-9-Methyl-DELTA±55100-octalin-1,6-dione (+/-)-9-Methyl-DELTA(5,10)-octalin-1,6-dioneWieland-Miescher ketone, racemic (±)-9-甲基-5(10)-辛-1,6-二酮 Wieland-Miescher 酮 魏兰德-米歇尔酮 Wieland-Miescher 酮 (±)-8a-甲基-3,4,8,8a-四氢-1,6(2H,7H)-萘二酮 3,4,8,8a-Tetrahydro-8a-methyl-(2H,7H)naphthalene-1,6-dione |
| MDL Number | MFCD00001687 |
| PubChem Substance ID | 24897092 |
| Beilstein Registry Number | 3201286 |
| CAS Number | 20007-72-1 |
| EC Number | 243-463-6 |
| Chemical Name Translation | (±)-8a-甲基-3,4,8,8a-四氢-1,6(2H,7H)-萘二酮 |
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分类
- Building Blocks, C11 to C12, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
- {SNA} Building Blocks, C11 to C12, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
相关文献及参考
- Beil. 7 ,IV,2109
- FT-IR 1 (1), 450:A / FT-IR 2 (1), 718:C / FT-NMR 1 (1), 717:B / IR-Spectra (3), 266:D / IR-Spectra (2), 237:H / NMR-Reference 2 (1), 414:B / RegBook 1 (1), 495:C / Structure Index 1 , 71:A:4 / Vapor Phase 3 , 541:C
- The enolate formed with LDA undergoes a double Michael reaction with methyl acrylate to give a tricyclic product: Tetrahedron, 51, 9891 (1995):
安全信息
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
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