Tricarbonyl(Cyclooctatetraene)Iron(II) 三羰基环辛四烯基铁

CAS 12093-05-9 MFCD00001755

化学结构图

12093-05-9
SMILES: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1C=CC=CC=CC=1

化学属性

TSCANo
Mol. FormulaC8H8Fe(CO)3
Mol. Weight244
Appearance red to brown xtl.
Stabilityair sensitive
Melting Point93-95°C

别名和识别编码

Chemical NameTricarbonyl(Cyclooctatetraene)Iron(II)
Synonym Tricarbonylcyclooctatraeneiron 1,3,5,7-Cyclooctatetraeneiron tricarbonyl Cyclooctatetraenetricarbonyliron NSC 167370 NSC 168049 Tricarbonyl[(1,2,3,4-η)-1,3,5,7-cyclooctatetraene]iron 三羰基环辛四烯基铁 Cyclooctatetraen-eisentricarbonyl Cyclooctatetraene iron tricarbonyl Iron, tricarbonyl[(1,2,3,4η<4>)-1,3,5,7-cyclooctatetraene]- Tricarbonylcyclooctatetraene iron
PubChem Substance ID87577508
Beilstein Registry Number5(4)1333
Chemical Name Translation三羰基环辛四烯基铁
MDL NumberMFCD00001755
CAS Number12093-05-9
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分类

  • {uni_hamburg}
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

安全信息

Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Packing GroupII
UN Number 3466 UN3466
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Air Sensitive
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P350
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Hazard Class6.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂
  1. CVD & ALD Precursors
  2. Iron
  1. Organometallics for CVD & ALD
  2. Iron

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