Benzophenone imine 二苯甲酮亚胺

CAS 1013-88-3 MFCD00001760

化学结构图

1013-88-3
SMILES: N=C(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC13H11N
Mol. Weight181.23
Density1.08
Refractive index1.6150 to 1.6190
Boiling Point282°C at 760 mmHg
Flash Point145 ºC
Melting Point-30°C
Solubility0.3 G/L (25 ºC)
TSCANo
Appearance 无色液体。沸点151-153℃（1.33kPa），相对密度1.080，折光率1.6169。

别名和识别编码

Chemical NameDiphenylmethanimineimine
Synonym Diphenylmethanimine {LY} Diphenylmethanimine {} {LY} Diphenylmethanimine {} {} {LY} Diphenylmethanimine {} {} {} {LY} Diphenylmethanimine {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylmethanimine {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00001760
CAS Number1013-88-3
EC Number250-023-7
Beilstein Registry Number1100371
PubChem Substance ID136809
Reaxys-RN1100371
Chemical Name Translation二苯甲酮亚胺
LabNetwork Molecule IDLN00169065
InChIInChI=1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
Canonical SMILESN=C(C1=CC=CC=C1)C2=CC=CC=C2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} B, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学
  • {SNA} B, Hematology and Histology, Stains & Dyes, A to Z, Stains and Dyes

产品应用

  • Useful in the preparation of nitrile ylide dimers.

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn;N Xi Xi,N,Xn
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 图谱信息:二苯甲酮亚胺(1013-88-3)红外图谱(IR1)
  • 用途一:用于有机合成。
  • Sigma Aldrich:1013-88-3(sigmaaldrich)
  • 方法一:将二苯甲酮肟加热，分解生成二苯甲酮和二苯甲酮亚胺，向反应混合物通入干燥的氯化氢气体，使二苯甲酮亚胺成盐析出，滤出亚胺盐，再用碱中和，即得游离的二苯甲酮亚胺。
  • 上游原料:乙酸乙酯 --> 乙醚 --> 氨 --> 苯甲腈 --> 二苯甲酮 --> 四氯化钛 --> 溴化苯基镁 --> 二苯甲酮肟
  • 下游产品:N-二苯亚甲基-甘氨酸叔丁酯
  • TCI Shanghai:二苯甲酮亚胺 Benzophenone Imine,>;95.0%(GC)(1013-88-3)
  • Acros Organics:二苯甲酮亚胺 Benzophenone imine, 97%(1013-88-3)
  • 二苯甲酮亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1912 二苯甲酮亚胺 Benzophenone Imine 25G 1100元 2014/06/02 B1912 二苯甲酮亚胺 Benzophenone Imine 5G 391元 2010/06/21 368590050 二苯甲酮亚胺 Benzophenone imine 97%, stabilized 5 GR 691元
  • MOL 文件:1013-88-3.mol
  • MSDS 信息:Benzophenone imine(1013-88-3).msds

系列性分类

  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Stains and Dyes - Hematology and Histology
  4. Stains & Dyes, A to Z - Stains and Dyes
  5. B - Stains & Dyes, A to Z
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Imines/Amidines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds

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