Benzyl Thiocyanate 硫氰酸苯甲酯

CAS 3012-37-1 MFCD00001832

化学结构图

3012-37-1
SMILES: N#CSCc1ccccc1

化学属性

Mol. FormulaC8H7NS
Mol. Weight149.21
Density1.32
Boiling Point256°C(lit.)
Melting Point40.0 to 43.0 deg-C
Flash Point110°(230°F)
TSCAYes
Solubility不溶

别名和识别编码

Chemical NameBenzyl Thiocyanate
CAS Number3012-37-1
EC Number221-144-2
Beilstein Registry Number6,460
MDL NumberMFCD00001832
Synonym Solvat 14 Benzylrhodonid 硫氰酸苄酯; 硫氰酸苯基甲基酯; 苄基硫氰酸酯 Beazyl thiocyanate 硫氰酸苄酯 BENZYL THIOCYANATE(SG) 硫氰化苄 Thiocyanic acid, phenylmethyl ester 苄基硫氰酸酯 Benzyl-thiocyanate 苄基硫氰酸 硫氰酸苄 a-Thiocyanatotoluene Toluene, alpha-thiocyanato- 苄基 硫氰酸酯, 98+% 硫代氰酸苄酯 Benzylthiocyanide 硫氰酸苯基甲基酯 2-Thiocyanatotoluene BENZYL THIOCYANATE 98% MIN alpha-Thiocyanatotoluene
PubChem Substance ID18170
Reaxys-RN1859726
Chemical Name Translation硫氰酸苯甲酯
Wiswesser Line NotationNCS1R
LabNetwork Molecule IDLN01037406
InChIInChI=1S/C8H7NS/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6H2
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiocyanates/Isothiocyanates

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S50 Do not mix with ... (to be specified by the manufacturer) 不要与……(由生产厂家指定)混合;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P305+P351+P338+P310
  • P301+P330+P331+P310
Hazard statements
  • H302+H312+H332
  • H302+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSXK8155000
Packing GroupII
UN Number 1759
Storage condition Moisture Sensitive 2-8°C
Hazard Codes Xn
Hazard Class8
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 16,870,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 17 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCBPBS Pesticide Biochemistry and Physiology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1971-  Volume(issue)/page/year:
   2,95,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Lungs, Thorax, or Respiration - respiratory stimulation
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   JJPAAZ Japanese Journal of Pharmacology.  (Japanese Pharmacological Soc.,
   c/o Dept. of Pharmacology, Faculty of Medicine, Kyoto Univ., Sakyo-ku, Kyoto
   606, Japan)  V.1-    1951-  Volume(issue)/page/year: 3,99,1954

其他信息

  • 毒性分级:剧毒
  • 海关编码:29309070
  • TCI Shanghai:硫氰酸苯甲酯 Benzyl Thiocyanate,>;99.0%(GC)(3012-37-1)
  • 急性毒性:腹腔-大鼠 LDL0: 40 毫克/公斤; 腹腔-小鼠 LD50: 17 毫克/公斤
  • 用途一:用于杀虫剂的制备
  • 储运特性:低温通风干燥; 与库房食品原料分开存放
  • 外观性质:橙红色结晶固体,有特殊刺激性气味。
  • Acros Organics:Benzyl thiocyanate, 97%(3012-37-1)
  • 硫氰酸苄酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0198 硫氰酸苯甲酯 Benzyl Thiocyanate 500G 1450元 2014/06/02 T0198 硫氰酸苯甲酯 Benzyl Thiocyanate 25G 172元 2010/06/21 106181000 硫氰酸苄酯 Benzyl thiocyanate 97% 100 GR 497元
  • Alfa Aesar:苄基硫氰酸酯,98+% Benzyl thiocyanate, 98+%(3012-37-1)
  • MSDS 信息:硫氰酸苄(3012-37-1).msds
  • Sigma Aldrich:3012-37-1(sigmaaldrich)
  • MOL 文件:3012-37-1.mol
  • 硫氰酸苄酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T0198 硫氰酸苯甲酯 Benzyl Thiocyanate 500G 1390元 2011/04/16 T0198 硫氰酸苯甲酯 Benzyl Thiocyanate 25G 162元 2010/06/21 106181000 硫氰酸苄酯 Benzyl thiocyanate 97% 100 GR 497元
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物,硫氧化物和氰化物烟雾
  • 敏感性:Moisture Sensitive
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类


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