2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈

CAS 58632-95-4 MFCD00001863

化学结构图

58632-95-4
SMILES: CC(C)(C)OC(=O)O/N=C(\C#N)c1ccccc1

化学属性

Mol. FormulaC13H14N2O3
Mol. Weight246
Melting Point85-88
Density1.422
TSCAYes
Solubilityinsoluble
Stability对湿度敏感

别名和识别编码

Chemical Name2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile
Synonym 2-(BOC-OXYIMINO)-2-PHENYLACETONITRILE 2-(Boc-oxyimino)-2-phenylacetonitrile 2-(Boc-oxyimino)-2-phenylacetonitrile~2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 2-(T-BUTOXYCARBONYLOXYIMINO)-2-PHENYLACETONITRILE 2-(叔-丁氧基碳酰胺)-2-苯乙腈, 98+% 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(叔丁氧羰基氧亚氨基)-2-苯基乙腈 2-T-BUTYLOXYCARBONYLOXYIMINO-2-PHENYL ACETONITRILE BOC-ON Boc-ON 2-t-Butyloxycarbonyloxyimino-2-phenyl acetonitrile Boc-ON, 98+% LABOTEST-BB LT00159655 N-TERT-BUTOXYCARBONYLOXYIMINO-2-PHENYLACETONITRILE [(CYANO-PHENYL-METHYLIDENE)AMINO] TERT-BUTYL CARBONATE tert-butyl alpha-cyanobenzylaminyl carbonate 叔丁基 叔丁基苯乙腈肟羰酸酯
Beilstein Registry Number2217296
PubChem Substance ID87563941
CAS Number58632-95-4
EC Number261-370-9
MDL NumberMFCD00001863
Reaxys-RN2217296
Chemical Name Translation2-(叔丁氧羰基氧亚氨基)-2-苯乙腈
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分类

  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Other Protecting and Derivatizing Reagents, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

产品应用

  • 肽合成中的氨基保护试剂。

相关文献及参考

  • Aldrich MSDS 1 , 211:C / Corp MSDS 1 (1), 469:B / FT-IR 2 (2), 3117:A / FT-IR 1 (2), 317:D / FT-NMR 1 (2), 1486:C / IR-Spectra (3), 1041:D / RegBook 1 (2), 2109:H / Sigma FT-IR 1 (2), 351:A / Structure Index 1 , 333:C:6
  • Fieser 6 ,91 / Fieser 10 ,61
  • Merck 14 ,10432
  • Reagent for the preparation of Boc-derivatives of amino acids, preferred on safety grounds to the unstable t-butyl azidoformate. In aqueous dioxane and in the presence of triethylamine as base, reaction is rapid at room temperature. The organic by-product, 2-hydroxyimino-2-phenylacetonitrile is easily removed by extraction into an organic phase: Tetrahedron Lett., 4393 (1975); Bull. Chem. Soc. Jpn., 50, 718 (1977). See Appendix 6.

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P332+P313+P362+P364
  • P405 Store locked up. 上锁保管。
  • P305+P351+P338+P337+P313
Storage condition Moisture Sensitive 0-10 0-10°C -20°C保存 2-8°C
UN Number 3439 3276 UN3439
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
RTECSDA0513600
Packing GroupIII
Hazard Codes Xn
Hazard Class6.1

其他信息

  • 下游产品:2-(甲基氨基)乙基氨基甲酸叔丁酯
  • 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B0988 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 25G 1220元 2011/04/16 B0988 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 5G 366元 2010/06/21 185890250 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 BOC-ON 99% 25 GR 1649元
  • MSDS 信息:2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile(58632-95-4).msds
  • Alfa Aesar:2-(叔-丁氧基碳酰胺)-2-苯乙腈,98+% Boc-ON, 98+%(58632-95-4)
  • MOL 文件:58632-95-4.mol
  • TCI Shanghai:2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile,>;98.0%(T)(58632-95-4)
  • Acros Organics:2-(叔-丁氧基碳酰胺)-2-苯乙腈 BOC-ON, 99%(58632-95-4)
  • Sigma Aldrich:58632-95-4(sigmaaldrich)
  • F:10-21
  • 海关编码:29280090
  • 敏感性:Moisture Sensitive

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Peptides - Biochemicals and Reagents
  4. Peptide Synthesis 多肽合成
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amine Protection - Peptide Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents
  1. Functional Group 官能团索引
  2. carbonic acid monoester
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Peptide Synthesis

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