• 原料直供
• 试剂商城
• 直接询价

分类

• Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
• {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, F, FM - FZ, Nitrogen Compounds, Organic Building Blocks
• {uni_hamburg} no charge; 1fragment
• {SNA} Alphabetic, Analytical Standards, Analytical/Chromatography, Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, F, FM -

相关文献及参考

• Beil. 2 ,IV,2219
• Aldrich MSDS 1 , 981:B / Corp MSDS 1 (1), 1750:A / FT-IR 1 (1), 844:A / FT-IR 2 (1), 1432:A / FT-NMR 1 (1), 1360:B / IR-Spectra (3), 504:C / NMR-Reference 2 (1), 702:B / RegBook 1 (1), 993:A / Sax 6 , 1460 / Sigma FT-IR 1 (2), 586:B / Structure Index 1 , 154:D:9 / Vapor Phase 3 , 803:D
• Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
• Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
• Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 38 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz.  (Darmstadt, Fed.
   Rep. Ger.)  V.1-25, 1951-75.  Volume(issue)/page/year: 19,225,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 132 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 12,157,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#05718

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 17 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,255,1990

其他信息

• 上游原料:马来酸酐 --> 马来酸 --> 富马酸 --> 富马酰胺
• 用途一:用于有机合成。
• MOL 文件:764-42-1.mol
• Alfa Aesar:富马酸腈,98+% Fumaronitrile, 98+%(764-42-1)
• 图谱信息:反丁烯二腈 (764-42-1)红外图谱(IR1) 反丁烯二腈 (764-42-1)核磁图( 1 HNMR) 反丁烯二腈 (764-42-1)Raman光谱 反丁烯二腈 (764-42-1)核磁图( 13 CNMR) 反丁烯二腈 (764-42-1)质谱(MS) 反丁烯二腈 (764-42-1)红外图谱(IR2)
• TCI Shanghai:反丁烯二腈 Fumaronitrile,>;98.0%(GC)(764-42-1)
• 方法一:由反丁烯二酸制得，反丁烯二酸的化学性质与顺丁烯二酸相似，反丁烯二酸加热至250-300℃转变顺丁烯二酸酐，反丁烯二酸也能生成一元及二元酯或酰胺，但不能生成一元酰氯而可生成二元酰氯。反丁烯二酸酯化生成反丁烯二酸二乙酯，再经酰胺化，脱水即得反丁烯二腈。1.酰胺化将反丁烯二酸二乙酯冷至0℃，搅拌下慢慢加入氨水，加完后再搅拌4h，过滤，用少量水洗一次，晾干，得反丁烯酰胺[627-64-5]。2.脱水将上述反丁烯酰胺与五氧化二磷混匀后，加热，减压蒸馏至无馏出物为止，得反丁烯二腈粗品。将粗品溶于苯中，摇动下倒入石油醚中，过滤，凉干即得成品。
• Acros Organics:富马二腈/丁烯二腈 Fumaronitrile, 98%(764-42-1)
• Sigma Aldrich:764-42-1(sigmaaldrich)