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分类

• Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
• {SNA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
• {SA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

• Can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide: J. Org. Chem., 36, 3050 (1971).

安全信息

GHS Symbol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 3,77,1897

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - nausea or vomiting
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 3,77,1897

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 3,77,1897

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - nausea or vomiting
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume

其他信息

• 外观性质:无色或浅黄色液体。
• 可燃性危险特性:明火可燃; 燃烧释放有毒氮氧化物烟雾
• Sigma Aldrich:544-13-8(sigmaaldrich)
• 用途一:用于有机合成。
• 灭火剂:干粉、泡沫、二氧化碳、砂土。
• Acros Organics:戊二腈 Glutaronitrile, 99%(544-13-8)
• F:3-10
• Alfa Aesar:戊二腈,99% Glutaronitrile, 99%(544-13-8)
• 戊二腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K4973001 戊二腈purum＞98％ 25ml 430元 2011/04/16 G0072 戊二腈 Glutaronitrile 25G 721元 2011/04/16 G0072 戊二腈 Glutaronitrile 250G 3660元
• 毒性分级:高毒
• 方法一:由二溴丙烷与氰化钠反应而得。将氰化钠溶于水，加入二溴丙烷的乙醇，冷却，滤去沉淀。将母液用乙酸乙酯提出取，用水洗涤提取液。经碳酸钾干燥后回收乙酸乙酯，剩余物进行减压蒸馏，收集144-147℃（1.73kPa）馏分即为成品，收率约80%。
• 上游原料:1,2-二溴丙烷
• 图谱信息:戊二腈(544-13-8)Raman光谱 戊二腈(544-13-8)核磁图( 13 CNMR) 戊二腈(544-13-8)质谱(MS) 戊二腈(544-13-8)核磁图( 1 HNMR) 戊二腈(544-13-8)红外图谱(IR1)
• TCI Shanghai:戊二腈 Glutaronitrile,>;96.0%(GC)(544-13-8)
• 敏感性:Hygroscopic
• 下游产品:戊二酸 --> 1,5-二氨基戊烷 --> 戊二酸二乙酯
• 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
• 急性毒性:口服-小鼠 LD50: 266 毫克/公斤
• MSDS 信息:戊二腈(544-13-8).msds
• MOL 文件:544-13-8.mol
• 类别:有毒物品