4-Bromophenylboronic acid 4-溴苯硼酸

CAS 5467-74-3 MFCD00002104

化学结构图

5467-74-3
SMILES: OB(O)c1ccc(Br)cc1

化学属性

Mol. FormulaC6H6BBrO2
Mol. Weight200.83
Melting Point284-288°C
TSCAT
Density1.67
Boiling Point315°C at 760 mmHg

别名和识别编码

Chemical Name4-Bromophenylboronic Acid (contains varying amounts of Anhydride)
CAS Number5467-74-3
Alfabeta NameBROMOPHENYLBORONICACID 4-
MDL NumberMFCD00002104
Synonym p-Bromophenylboric acid {LY} p-Bromophenylboric acid para-bromophenylboric acid {} {LY} p-Bromophenylboric acid {} {} {LY} p-Bromophenylboric acid {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} p-Bromophenylboric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID79599
EC Number226-779-9
Beilstein Registry Number2936347
Reaxys-RN2936347
Chemical Name Translation4-溴苯硼酸
InChIKeyQBLFZIBJXUQVRF-UHFFFAOYSA-N
Wiswesser Line NotationQBQR DE
LabNetwork Molecule IDLN00159009
InChIInChI=1S/C6H6BBrO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
Canonical SMILESBrC1=CC=C(B(O)O)C=C1
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

产品应用

  • 4-Bromophenylboric acid

相关文献及参考

  • Weston, G.S., et al.: J. Med. Chem., 41, 4577 (1998),
  • Carbonylative cross-coupling with iodobenzenes and CO, catalyzed by trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491, gives unsymmetrical diaryl ketones: Tetrahedron Lett., 34, 7595 (1993); J. Org. Chem., 63, 4726 (1998). For reactions of boronic acids, see Appendix 5.
  • 7. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
  • Beilstein:16(2)638
  • 5. Qi, Q.; Shen, Q.; Lu, L., Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
  • GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).
  • 6. Shen, K.; Han, X.; Lu, X., Cationic Pd(II)-Catalyzed Highly Enantioselective Arylative Cyclization of Alkyne-Tethered Enals or Enones Initiated by Carbopalladation of Alkynes with Arylboronic Acids Org. Lett. 7th ed., 14 , 1756-1759, (2012) 摘要

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSCY8650000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03201

其他信息

  • Sigma Aldrich:5467-74-3(sigmaaldrich)
  • TCI Shanghai:4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride)(5467-74-3)
  • TSCA:T
  • MSDS 信息:4-Bromobenzeneboronic acid(5467-74-3).msds
  • 4-溴苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 1G 80元 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 25G 735元 2014/06/02 B1858 4-溴苯硼酸(含有数量不等的酸酐) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 5G 210元
  • MOL 文件:5467-74-3.mol
  • Hazard Note:Irritant
  • Acros Organics:4-Bromophenylboronic acid, 98%(5467-74-3)
  • Alfa Aesar:4-溴苯硼酸,97+% 4-Bromobenzeneboronic acid, 97+%(5467-74-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Monosubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl

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